Organic acid chlorides, RCOCl, react with trans-[W(N2)2(dpe)2](dpe = Ph2PCH2CH2PPh2) to produce complexes [(dpe)2Cl2W(N2HCOR)] from which HCl can be removed to form chelated aroyl- and acyl-azo-N,O-complexes, [(dpe)2ClW(–N = N–COR)].
J. Chatt, G. A. Heath and G. J. Leigh, J. Chem. Soc., Chem. Commun., 1972, 444 DOI: 10.1039/C39720000444
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