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Issue 8, 1972
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2,2-Dimethyl-1,1,1,1-tetracarbonyl-1-ferra-2-silacyclopentane: insertion of [Fe(CO)4] into a strained organosilicon ring

Abstract

The strained organosilicon heterocycle, 1,1-dimethyl-1-silacyclobutane reacts with nonacarbonyldi-iron to give a new type of binuclear chelate complex, (CO)4[graphic omitted]iMe2, which is thermally stable, but chemically reactive.

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Article type: Paper
DOI: 10.1039/C39720000445
J. Chem. Soc., Chem. Commun., 1972, 445-446

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    2,2-Dimethyl-1,1,1,1-tetracarbonyl-1-ferra-2-silacyclopentane: insertion of [Fe(CO)4] into a strained organosilicon ring

    C. S. Cundy and M. F. Lappert, J. Chem. Soc., Chem. Commun., 1972, 445
    DOI: 10.1039/C39720000445

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