Sn3BrF5 contains an infinite tin(II) fluoride cationic network and free bromide ions, each tin has a pyramidal three-co-ordinated environment but there are two types of tin site in the structure.
J. D. Donaldson and D. C. Puxley, J. Chem. Soc., Chem. Commun., 1972, 289 DOI: 10.1039/C39720000289
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