Issue 3, 1972
From the journal:

Journal of the Chemical Society, Chemical Communications

The reduction of thioether and carboxylate chelates of cobalt(III) by chromium(II)

Michael Gilroy,   Frank A. Sedor  and  Larry E. Bennett  

Abstract

The rates of reduction by chromium(II) of Co(en)2(NH2CH2CO2)2+(carboxylate-bridged), Co(en)2(O2CCH2SMe)2+(carboxylate-bridged) and Co(en)2(NH2CH2SMe)3+(outer-sphere) indicate reactivity advantages for chelated bridging carboxylate and nonbridging cis thioether ligands in inner-sphere reactions and a high reactivity associated with thioether functions in outersphere reactions.

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Article information

DOI
https://doi.org/10.1039/C39720000181
Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 181-182

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The reduction of thioether and carboxylate chelates of cobalt(III) by chromium(II)

M. Gilroy, F. A. Sedor and L. E. Bennett, J. Chem. Soc., Chem. Commun., 1972, 181 DOI: 10.1039/C39720000181

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