Acidity dependent changes in the π–π* and n–π* absorption bands of aliphatic amides indicate that the N-protonated species constitutes no more than a very small fraction (ca. 10–3) of the total protonated amide.
H. Benderly and K. Rosenheck, J. Chem. Soc., Chem. Commun., 1972, 179 DOI: 10.1039/C39720000179
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