Circular dichroism of ketones at 185–195 nm
Abstract
Many steroid ketones exhibit a strong Cotton effect in the region of 190 nm: α- and β-axial methyl or methylene groups appear to make large contributions, with signs determined by the Octant rule.
Many steroid ketones exhibit a strong Cotton effect in the region of 190 nm: α- and β-axial methyl or methylene groups appear to make large contributions, with signs determined by the Octant rule.
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D. N. Kirk, W. Klyne, W. P. Mose and E. Otto, J. Chem. Soc., Chem. Commun., 1972, 35 DOI: 10.1039/C39720000035
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