Issue 0, 1971
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Vibrational and 1H nuclear magnetic resonance spectroscopic studies of some complexes of platinum(II) and palladium(II) containing methylthio bridges

P. L. Goggin,   R. J. Goodfellow  and  F. J. S. Reed  

Abstract

Reactions of methanethiol with some halogen-bridged compounds M2X4(YMe3)2 and M2X2(YMe3)4(BF4)2(M = Pd or Pt, X = Cl or Br, and Y = P or As) are reported and 1H n.m.r., i.r. (below 800 cm–1) and Raman spectra of the products, M2X3SMe(YMe3)2, M2X2(SMe)2(YMe3)2, and Pt2(SMe)2(YMe3)4(BF4)2 discussed. The results demonstrate that the trans-influence of the methylthio-group is much greater than that of chloride or bromide. The significance of non-bonded ligand electrons on the effectiveness of metal–ligand bonding is discussed.

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Article information

DOI
https://doi.org/10.1039/J19710002031
Article type
Paper

J. Chem. Soc. A, 1971, 2031-2038

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Vibrational and 1H nuclear magnetic resonance spectroscopic studies of some complexes of platinum(II) and palladium(II) containing methylthio bridges

P. L. Goggin, R. J. Goodfellow and F. J. S. Reed, J. Chem. Soc. A, 1971, 2031 DOI: 10.1039/J19710002031

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