The silyl alkylation procedure has furnished the first thiazolo [5,4-d]pyrimidine nucleoside (both α and β anomers isolated and characterized), and the site of alkylation has been established by a comparison of the u.v. spectra of the nucleoside and model N-methyl compounds.
C. L. Schmidt, W. J. Rusho and L. B. Townsend, J. Chem. Soc. D, 1971, 1515 DOI: 10.1039/C29710001515
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