The synthesis of h5-cycloheptatrienylmanganesetricarbonyl by low temperature photochemical decarbonylation of the acyl manganese species (2) is described, and the properties of this molecule are compared to those of the isoelectronic iron cation.
T. H. Whitesides and R. A. Budnik, J. Chem. Soc. D, 1971, 1514 DOI: 10.1039/C29710001514
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