Issue 21, 1971

Photodecarbonylation of 1,3-diphenylinden-2-one adducts; 1,5-sigmatropic shifts in sterically stabilised o-quinodimethanes

Abstract

Photodecarbonylation of the 1,3-diphenylinden-2-one–substituted maleimide adducts (II) and (VI) gave the sterically stabilised o-quinodimethanes (V; R1= R2= R3= Me) and (V; R1, R2=[CH2]4, R3= Me) in which 1,5-sigmatropic shift of the imido-group is preferred to alkyl migration.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 1356-1357

Photodecarbonylation of 1,3-diphenylinden-2-one adducts; 1,5-sigmatropic shifts in sterically stabilised o-quinodimethanes

D. W. Jones and G. Kneen, J. Chem. Soc. D, 1971, 1356 DOI: 10.1039/C29710001356

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