Reactions in protic solvents of 2-hydroxyalkyltriphenylphosphonium salts with base and of triphenylphosphine with propylene oxide produce numerous unexpected products, thereby revealing a much wider scope of reactivity for the phosphobetaine intermediates of these reactions than was previously recognized.
J. W. Rakshys and S. V. McKinley, J. Chem. Soc. D, 1971, 1336 DOI: 10.1039/C29710001336
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