Metallation of S-benzyl methyl sulphoxide followed by quenching with acetone gives a mixture of diastereomers in a 15 : 1 ratio; the major isomer is shown to have the R configuration of carbon and a synthesis of optically active epoxides from optically active sulphoxdes is described.
T. Durst, R. Viau, R. Van Den Elzen and C. H. Nguyen, J. Chem. Soc. D, 1971, 1334b DOI: 10.1039/C2971001334B
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