Radical-anions and dianions of methylphenylacetylene. The role of dianions in protonation and electron-transfer processes
Abstract
Kinetic and product studies show that electron transfer to methyl(phenyl)acetylene (MPA) gives its dianions (MPA2–,2Na+) which are protonated by MPA yielding Ph![[C with combining macron]](https://www.rsc.org/images/entities/char_0043_0304.gif)
CHMe,Na+ and Ph![[C with combining macron]](https://www.rsc.org/images/entities/char_0043_0304.gif)
C
CH2,Na+ as the products.
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