Ready insertion of ethylene of propene into the Pt–H bond of PtII hydrido–complexes, which leads to good yields of ethyl or n-propyl derivatives, involves displacement of the ligand trans to the hydridic hydrogen in a cationic species, giving a cationic hydrido-olefin complex as intermediate.
H. C. Clark and H. Kurosawa, J. Chem. Soc. D, 1971, 957 DOI: 10.1039/C29710000957
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