Irradiation of [Fe(CO)3π-C4Me4] with hexafluoroacetone gives [[graphic ommitted](CO)2π-C4Me4], whereas, tetrafluoroethylene and hexafluoropropene afford novel π-allylic complexes, in which the fluoro-olefin links the C4 ring to the metal atom.
A. Bond and M. Green, J. Chem. Soc. D, 1971, 12 DOI: 10.1039/C29710000012
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