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Issue 16, 1971
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Crystallographic evidence of the three-centre bond in hexamethyldialuminium

Abstract

Three dimensional X-ray data collected at approximately –170 °C clearly located all hydrogen positions in hexamethyldialuminium and confirmed that the bridging methyl groups form three-centre bonds with the aluminium atoms, without aluminium–hydrogen bridging.

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Article information


J. Chem. Soc. D, 1971, 911-912
Article type
Paper

Crystallographic evidence of the three-centre bond in hexamethyldialuminium

J. C. Huffman and W. E. Streib, J. Chem. Soc. D, 1971, 911
DOI: 10.1039/C29710000911

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