1  H nuclear magnetic resonance evidence for the pseudo-octahedral geometry and ready racemization of [1,1,1-tris(pyridine-2-carboxaldiminomethyl)ethane]iron(II)

F. L. Urbach; S. O. Wandiga

doi:10.1039/C2970001572A

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¹H nuclear magnetic resonance evidence for the pseudo-octahedral geometry and ready racemization of [1,1,1-tris(pyridine-2-carboxaldiminomethyl)ethane]iron(II)

F. L. Urbach and S. O. Wandiga

Abstract

From ¹H n.m.r. studies the trigonal hexadentate complex, [1,1,1-tris(pyridine-2-carboxaldiminomethyl)ethane]iron(II), is shown to possess a pseudo-octahedral geometry and to racemize readily.

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DOI: https://doi.org/10.1039/C2970001572A
Article type: Paper

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J. Chem. Soc. D, 1970, 1572a-1572a

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¹ H nuclear magnetic resonance evidence for the pseudo-octahedral geometry and ready racemization of [1,1,1-tris(pyridine-2-carboxaldiminomethyl)ethane]iron(II)

F. L. Urbach and S. O. Wandiga, J. Chem. Soc. D, 1970, 1572a DOI: 10.1039/C2970001572A

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Journal of the Chemical Society D: Chemical Communications