The rearrangement of the 4,5- to 4,6-bisheptafluoroisopropylpyridazine (3)→(4) in the presence of fluoride ion is reported, and the importance of this reaction in the formation of the trisheptafluoroisopropyl derivative (5) is indicated.
R. D. Chambers, Yu. A. Cheburkov, J. A. H. MacBride and W. K. R. Musgrave, J. Chem. Soc. D, 1970, 1647 DOI: 10.1039/C29700001647
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