Issue 23, 1970
From the journal:

Journal of the Chemical Society D: Chemical Communications

The proton affinity of organometallic compounds possessing an N-alkylimino-group

P. M. Treichel,   J. J. Benedict,   R. W. Hess  and  J. P. Stenson  

Abstract

(C5H5Fe)2(CO)3(CNMe) is readily protonated in dilute aqueous acid to give a stable complex, (C5H5Fe)2(CO)3(CNHMe)+, containing a bridging 〉C = NHMe group: treatment of C5H5Fe(CNMe)3+ and C5H4MeMn(NO)(CNMe)2+ with C6F5Li give C5H5Fe(CNMe)2C(C6F5)= NHMe+ and C5H4MeMn(NO)(CNMe)C(C6F5)= NHMe+, respectively, as major products, arising from protonation of the expected product during work-up: (Ph3P)2Pt-[C(Ph)= NMe]I is protonated by NH4PF6 to give (Ph3P)2Pt[C(Ph)= NHMe]I+PF6–.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C29700001627
Article type
Paper

J. Chem. Soc. D, 1970, 1627-1627

Permissions

Request permissions

The proton affinity of organometallic compounds possessing an N-alkylimino-group

P. M. Treichel, J. J. Benedict, R. W. Hess and J. P. Stenson, J. Chem. Soc. D, 1970, 1627 DOI: 10.1039/C29700001627

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements