Suspensions of (Et3P)2Pt(CNMe)Cl+Cl– or (Ph3P]2Pt(CNMe)X+X–(X = Cl, Br) in benzene under reflux yield the complexes (Et3P)2Pt(CN)Cl and (Ph3P)2Pt(CN)X: the analogous reaction with (Ph3P)2Pt(CNMe)2I+ gave (Ph3P)2Pt(CNMe)CNI, together with a small amount of (Ph3P)2Pt(CN)2.
P. M. Treichel and R. W. Hess, J. Chem. Soc. D, 1970, 1626 DOI: 10.1039/C29700001626
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