Oxygenation reactions of diperoxychromium(VI) oxide etherate (CrO5–OEt2). Possible role of singlet oxygen in the isolation of 1,2,3,4-tetraphenyl-5,6-dioxabicyclo[2,2,1]hept-2-en-7-one (tetracyclone endoperoxide)

Henry W.-S. Chan

doi:10.1039/C29700001550

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Oxygenation reactions of diperoxychromium(VI) oxide etherate (CrO₅–OEt₂). Possible role of singlet oxygen in the isolation of 1,2,3,4-tetraphenyl-5,6-dioxabicyclo[2,2,1]hept-2-en-7-one (tetracyclone endoperoxide)

Henry W.-S. Chan

Abstract

The title epidioxy-ketone was isolated using diperoxychromium(VI) oxide etherate as an oxygenating reagent in a reaction which may involve singlet oxygen as an intermediate.

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DOI: https://doi.org/10.1039/C29700001550
Article type: Paper

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J. Chem. Soc. D, 1970, 1550-1551

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Oxygenation reactions of diperoxychromium(VI) oxide etherate (CrO₅–OEt₂). Possible role of singlet oxygen in the isolation of 1,2,3,4-tetraphenyl-5,6-dioxabicyclo[2,2,1]hept-2-en-7-one (tetracyclone endoperoxide)

H. W.-S. Chan, J. Chem. Soc. D, 1970, 1550 DOI: 10.1039/C29700001550

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Journal of the Chemical Society D: Chemical Communications

Oxygenation reactions of diperoxychromium(VI) oxide etherate (CrO₅–OEt₂). Possible role of singlet oxygen in the isolation of 1,2,3,4-tetraphenyl-5,6-dioxabicyclo[2,2,1]hept-2-en-7-one (tetracyclone endoperoxide)

Abstract

Article information

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Oxygenation reactions of diperoxychromium(VI) oxide etherate (CrO₅–OEt₂). Possible role of singlet oxygen in the isolation of 1,2,3,4-tetraphenyl-5,6-dioxabicyclo[2,2,1]hept-2-en-7-one (tetracyclone endoperoxide)

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