Comparison of the products from reactions of diazomethane and diazoethane with pyranosid-2-uloses provides new information about the importance of steric factors in diazoalkane–cyclic ketone interactions; the reaction of diazoethane with pyranosid-2-uloses is a potentially useful route to higher branched-chain sugars.
T. D. Inch, G. J. Lewis, R. P. Peel and N. Williams, J. Chem. Soc. D, 1970, 1549 DOI: 10.1039/C29700001549
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