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Because of chemical shift perturbations by ion-pair aggregation, the sense of n.m.r. spectral non-equivalence observed for diastereomeric salts may not be readily correlated with the relative (or absolute) configurations of the diastereomers.
W. H. Pirkle, J. Chem. Soc. D, 1970, 1525 DOI: 10.1039/C29700001525
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