2,2-Dimethylphosphetans with chlorine or bromine give but-3-enylhalogenophosphines which cyclise to phospholenes on heating or on treatment with halogen and to phospholenes and/or phosphetan oxides with aluminium chloride.
J. R. Corfield, M. J. P. Harger, R. K. Oram, D. J. H. Smith and S. Trippett, J. Chem. Soc. D, 1970, 1350 DOI: 10.1039/C29700001350
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