A common stereoelectronic requirement is satisfied in the epimerisation by weak alkali of the cis-alcohols, (I), (II), (III), and (IV), into the trans-epimers, (V), (VI)(VII), and (VIII), respectively, and that of the β-axial alcohol (XVIII) of the gibberellin series into its α-equatorial epimer (XIX).
E. Fujita and Y. Nagao, J. Chem. Soc. D, 1970, 1211 DOI: 10.1039/C29700001211
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