Crystal structure analysis of Tl4P4O12 shows it to consist of tetrameric ring anions P4O124– of symmetry ![[4 with combining macron]](https://www.rsc.org/images/entities/char_0034_0304.gif)
(S4): thallium atoms in two different sites form O ⋯ Tl ⋯ O bridges between the rings.
J. K. Fawcett, V. Kocman, S. C. Nyburg and R. J. O'Brien, J. Chem. Soc. D, 1970, 1213 DOI: 10.1039/C29700001213
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