The 1 : 1 and 1 : 2 tertiary phosphine adducts of Pd(S2PPh2)2, originally formulated as five- and six-co-ordinate complexes, respectively, are probably both four-co-ordinate.
J. M. C. Alison and T. A. Stephenson, J. Chem. Soc. D, 1970, 1092 DOI: 10.1039/C29700001092
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