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Issue 13, 1970
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Carbon and oxygen isotope effects in the decarbonylation of benzoylformic acid in concentrated sulphuric acid

Abstract

Kinetic isotope effects for carbon and oxygen for the decarbonylation of benzoylformic acid in concentrated sulphuric acid have been measured, which together with measurements on isotopic exchange of oxygen with the solvent, support a mechanism in which C–O bond rupture occurs in the rate-determining step.

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Article type: Paper
DOI: 10.1039/C29700000802
Citation: J. Chem. Soc. D, 1970,0, 802-803
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    Carbon and oxygen isotope effects in the decarbonylation of benzoylformic acid in concentrated sulphuric acid

    Z. Margolin and D. Samuel, J. Chem. Soc. D, 1970, 0, 802
    DOI: 10.1039/C29700000802

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