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Issue 18, 1970
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Rearrangement reactions of 1-NN-dimethylaminobenzobenzobarrelene derivatives (benzobarrelene = 1,4-dihydro-1,4-ethenonaphthalene)

Abstract

The title compounds are rearranged to 4-NN-dimethylaminobiaryl derivatives on being heated in protic media; however, that the driving force for the rearrangement does not involve the aromatisation step has been shown by the isolation of a 4,4-disubstituted cyclohexadienone in one example.

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Article information


J. Chem. Soc. D, 1970, 1184-1184
Article type
Paper

Rearrangement reactions of 1-NN-dimethylaminobenzobenzobarrelene derivatives (benzobarrelene = 1,4-dihydro-1,4-ethenonaphthalene)

H. Heaney and S. V. Ley, J. Chem. Soc. D, 1970, 1184
DOI: 10.1039/C29700001184

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