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Tautomerism of the dimeric 3-methylisoxazol-5-one, a vinylogous hydroxamic acid, is discussed. Spectrometry reveals that the NH form (I) and/or (V) predominates in organic solution. However, in aqueous solution dissociation into the anion is suggested.
T. Nishiwaki, J. Chem. Soc. C, 1969, 245 DOI: 10.1039/J39690000245
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