Issue 0, 1969
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


The oxidative addition of iodomethane to trans-halogenocarbonylbis(triarylphosphine)rhodium(I) and the subsequent isomerisation via methyl transfer to an acetyl complex

I. C. Douek  and  G. Wilkinson  

Abstract

A study has been made of the effects of the ligands, halide, X–, and tertiary phosphine, R3P, on the oxidative addition of iodomethane to trans-halogenocarbonylbis(tertiaryphosphine)rhodium(I), trans-RhX(CO)(PR3)2 to give, initially, RhXIMe(CO)(PR3)2 and finally, the acetyl complex RhXI(COMe)(PR3)2. Approximate kinetic and equilibrium data have been determined.

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Article information

DOI
https://doi.org/10.1039/J19690002604
Article type
Paper

J. Chem. Soc. A, 1969, 2604-2610

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The oxidative addition of iodomethane to trans-halogenocarbonylbis(triarylphosphine)rhodium(I) and the subsequent isomerisation via methyl transfer to an acetyl complex

I. C. Douek and G. Wilkinson, J. Chem. Soc. A, 1969, 2604 DOI: 10.1039/J19690002604

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