Issue 0, 1969
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Nitrido-, oxo-, and imido-complexes. Part I. Nitrido-cyano-complexes of rhenium(V)

N. P. Johnson  

Abstract

ReNBr2(PPh3)2 has been treated with potassium cyanide in methanol to give K2[ReN(CN)4],H2O and K3[ReN(CN)5]. The interconversion of these two salts has been studied, and salts containing other cations have been prepared. The i.r. spectrum of K2[ReN(CN)4],H2O is consistent with [ReN(CN)4H2O]2– ions in solution, and infinite chains of alternating Re–N in the solid, with four cyanide groups round each rhenium atom.

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Article information

DOI
https://doi.org/10.1039/J19690001843
Article type
Paper

J. Chem. Soc. A, 1969, 1843-1845

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Nitrido-, oxo-, and imido-complexes. Part I. Nitrido-cyano-complexes of rhenium(V)

N. P. Johnson, J. Chem. Soc. A, 1969, 1843 DOI: 10.1039/J19690001843

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