Ligand exchange kinetics of metal dimethyl sulphoxide complexes, ML62+, in mixed solvents
Abstract
The ligand exchange kinetics of ML62+[M = CoII or NiII, L = dimethyl sulphoxide (DMSO)] in DMSO and the mixed solvents DMSO–MeNO2 and DMSO–CH2Cl2 are independent of the composition of the solvent.