The compound [Pt2(acac)2(allyl)2] is shown by X-ray diffraction to have the platinum atoms bridged by allyl groups, and n.m.r. shows the complexes [Pt(2-methylallyl)2] and [Pt2Cl2(2-methylallyl)2] to exist as syn- and anti-isomers, with symmetrically bonded π-2-methylallylic groups.
W. S. McDonald, B. E. Mann, G. Raper, B. L. Shaw and G. Shaw, J. Chem. Soc. D, 1969, 1254b DOI: 10.1039/C2969001254B
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