The more stable stereoisomer of 2-ethoxy-4-methyl-1,3,2-dioxaphosphorinane has the trans-configuration and assumes a chair conformation with equatorial methyl and axial ethoxy-group, whilst the less stable isomer has the cis-configuration and, at room temperature, adopts a rapidly flipping chair conformation.
C. Bodkin and P. Simpson, J. Chem. Soc. D, 1969, 829b DOI: 10.1039/C2969000829B
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