Volume 64, 1968
From the journal:

Transactions of the Faraday Society

Mercury photosensitized decomposition of fluorinated methanes

J. D. Allen  and  M. C. Flowers  

Abstract

No evidence for chemical quenching of Hg 63P1 by CF4, CF3H or CF2H2 has been found. Chemical quenching by CH3F gives rise to a wide variety of fluorinated and non-fluorinated products. The quenching rate constant is approximately 1 × 105 l. mole–1 sec–1. A mechanism for formation of reaction products is proposed involving quenching via C—H bond fission and the participation of singlet methylene generated from chemically activated methyl fluoride.

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Article information

DOI
https://doi.org/10.1039/TF9686403300
Article type
Paper

Trans. Faraday Soc., 1968,64, 3300-3310

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Mercury photosensitized decomposition of fluorinated methanes

J. D. Allen and M. C. Flowers, Trans. Faraday Soc., 1968, 64, 3300 DOI: 10.1039/TF9686403300

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