A Calvet microcalorimeter has been used to measure the heats at 30° of the dissociations CoL2Cl2(cryst.)→ CoCL2(cryst.)+ 2L(liq.), where L = pyridine or α-picoline. The heat of the reaction Co(PPh3)2Cl2(cryst.)→ CoCl2(cryst.)+ 2PPh3(cryst.) has also been determined at 25° from solution calorimetry, by use of an adiabatic reaction calorimeter.
G. Beech, S. J. Ashcroft and C. T. Mortimer, J. Chem. Soc. A, 1967, 929 DOI: 10.1039/J19670000929
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