Open Access Article
Lena A.
Mittmann
*a,
Javier Sanz
Rodrigo
a,
Eugène
Bertin
a,
Giulia
Dalmonte
ab,
Jean-Claude
Grivel
b,
Ivano E.
Castelli
b and
Andrea
Crovetto
*a
aNational Centre for Nano Fabrication and Characterization (DTU Nanolab), Technical University of Denmark, 2800 Kongens Lyngby, Denmark. E-mail: mittma@dtu.dk; ancro@dtu.dk
bDepartment of Energy Conversion and Storage (DTU Energy), Technical University of Denmark, 2800 Kongens Lyngby, Denmark
First published on 30th January 2026
Correction for ‘Large-area thin-film synthesis of photoactive Cu3PS4 thiophosphate semiconductor with 0–14 pH stability range’ by Lena A. Mittmann et al., Chem. Sci., 2025, 16, 21862–21873, https://doi.org/10.1039/D5SC05882A.
At the CBM, the dominant antibonding interactions are between S 3p states and P 4s states, with a higher P 4s character at the Γ point than at the CBM on the Γ–X path. Again, the situation is analogous to S 3p/In 6s mixing at the CBM of chalcopyrites and S 3p/Sn 6s mixing in kesterites, pointing to the similar role of P, In, and Sn across these copper-based sulfides, and to phosphorus behaving much like a post-transition metal cation.
Here, P 4s should be P 3s, In 6s should be In 5s and Sn 6s should be Sn 5s. This typographical error does not affect any of the conclusions drawn within the manuscript.
The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.
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