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Correction: Large-area thin-film synthesis of photoactive Cu3PS4 thiophosphate semiconductor with 0–14 pH stability range

Lena A. Mittmann *a, Javier Sanz Rodrigo a, Eugène Bertin a, Giulia Dalmonte ab, Jean-Claude Grivel b, Ivano E. Castelli b and Andrea Crovetto *a
aNational Centre for Nano Fabrication and Characterization (DTU Nanolab), Technical University of Denmark, 2800 Kongens Lyngby, Denmark. E-mail: mittma@dtu.dk; ancro@dtu.dk
bDepartment of Energy Conversion and Storage (DTU Energy), Technical University of Denmark, 2800 Kongens Lyngby, Denmark

Received 14th January 2026 , Accepted 14th January 2026

First published on 30th January 2026


Abstract

Correction for ‘Large-area thin-film synthesis of photoactive Cu3PS4 thiophosphate semiconductor with 0–14 pH stability range’ by Lena A. Mittmann et al., Chem. Sci., 2025, 16, 21862–21873, https://doi.org/10.1039/D5SC05882A.


The original version of this article contained typographical errors in the following section of text:

At the CBM, the dominant antibonding interactions are between S 3p states and P 4s states, with a higher P 4s character at the Γ point than at the CBM on the Γ–X path. Again, the situation is analogous to S 3p/In 6s mixing at the CBM of chalcopyrites and S 3p/Sn 6s mixing in kesterites, pointing to the similar role of P, In, and Sn across these copper-based sulfides, and to phosphorus behaving much like a post-transition metal cation.

Here, P 4s should be P 3s, In 6s should be In 5s and Sn 6s should be Sn 5s. This typographical error does not affect any of the conclusions drawn within the manuscript.

The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.


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