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Correction: Cu(I)-catalyzed 1,2-carbofluorination of unactivated alkenes enabled by N-fluorobenzamides via free radical relay

Hong Jia, Haifeng Qiaoa, Boyi Wanga, Tianyu Lua, Weixing Changa, Lingyan Liu*a and Jing Li*ab
aState Key Laboratory and Institute of Elemento-Organic Chemistry, National Engineering Research Center of Pesticide, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Weijin Road 94#, Nankai District, Tianjin, 300071, P. R. China. E-mail: liulingyan@nankai.edu.cn
bCollaborative Innovation Center of Chemical Science and, Engineering (Tianjin), 300071, China. E-mail: lijing@nankai.edu.cn

Received 13th March 2026 , Accepted 13th March 2026

First published on 23rd March 2026


Abstract

Correction for ‘Cu(I)-catalyzed 1,2-carbofluorination of unactivated alkenes enabled by N-fluorobenzamides via free radical relay’ by Hong Ji et al., Org. Chem. Front., 2026, https://doi.org/10.1039/d5qo01763g.


The authors regret that Table 2, Scheme 2d and Scheme 4 were incorrect in the original article. The correct table and schemes are shown here.
Table 1 The scope for the 1,2-carbofluorination reaction of unactivated alkenesa
a Under standard conditions, N-fluorobenzamide 1 (0.2 mmol, 2.0 equiv.), 8-aminoquinoline-protected vinyl acetamide 2 (0.1 mmol), and cuprous chloride (2.0 mg, 0.02 mmol, 20 mol%) were added to a 10 mL Schlenk tube equipped with a stirring bar. The mixture was protected under argon gas, and finally, 2.0 mL of CHCl3 was added. Under the condition of 70 °C (oil bath), the mixture was stirred for 4 hours. Isolated yield.
image file: d6qo90022d-u1.tif



image file: d6qo90022d-s2.tif
Scheme 1 (d) Late transformation of 3a.

image file: d6qo90022d-s4.tif
Scheme 2 The plausible mechanism of N-fluorobenzamide enabling 1,2-carbofluorination bifuncationalization of unactivated alkenes.

The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.


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