Taha
Sheheryar
a,
Ye
Tian
b,
Bo
Lv
*a,
Xiuqin
Chu
*c and
Jinhui
Shi
*a
aKey Laboratory of In-Fiber Integrated Optics of Ministry of Education, College of Physics and Optoelectronic Engineering, Harbin Engineering University, Harbin 150001, Heilongjiang Province, China. E-mail: lb19840313@126.com; shijinhui@hrbeu.edu.cn
bCollege of Automation, Nanjing University of Science and Technology, Nanjing 210000, Jiangsu Province, China
cKey Laboratory of High-Speed Circuit Design and EMC Ministry of Education, Xidian University, Xi’an, 710071, China. E-mail: xqchu@mail.xidian.edu.cn
First published on 27th January 2025
In this paper, we designed a novel tunable terahertz (THz) absorber that has unique properties of graphene integrated within a dual-layer metasurface structure. The proposed absorber demonstrates excellent performance by achieving eight distinct absorption peaks from 3.9 THz to 9.73 THz with an average absorption efficiency of 99.3%. This is achieved through the tunable surface conductivity of graphene which enables dynamic modulation of resonant frequencies via chemical potential adjustment. The design includes a gold base layer for total reflection, gallium arsenide (GaAs) dielectric spacers for optimum impedance matching and graphene patches to introduce multi-band absorption modes. Simulation results show the absorber's tunability, polarization insensitivity and angular stability which makes it highly adaptable for applications in medical diagnostics, material characterization, security screening and terahertz sensing. The proposed absorber's innovative architecture and simple design offers a versatile solution for the evolving demands of modern terahertz technologies.
Traditional metamaterial absorbers (MMAs) naturally rely on metal–dielectric–metal configuration which are usually limited by their fixed operational frequency bands. Once these absorbers are fabricated their performance at specific frequencies cannot be adjusted. This limits their usefulness and applicability in active environments. The unique ability to selectively manipulate and absorb multiple distinct frequencies provides significant opportunities for advancing signal processing capabilities that include enhancement in imaging resolution and strengthening security protocols across a range of applications. The integration of graphene into these designs provide a transformative solution to the said restraint. When coupled with micro or nanostructures, graphene can engage in surface plasmon resonance especially in the terahertz and infrared regions.11 One of the most significant advantages of graphene-based metamaterial absorbers is the ability to dynamically adjust the absorber's operational frequency band. This is achieved through the external modulation of graphene's chemical potential via an applied bias voltage which effectively alters its surface conductivity distribution.12,13 Tuning the chemical potential results in a change in the resonant frequency of the absorber which can be precisely controlled and this offers unparalleled flexibility in adapting to different terahertz frequencies.14–16 This tunability is an essential feature for terahertz applications where real-time adjustment is vital for various sensing and communication applications.17,18
In addition to graphene, other materials are frequently used in combination with graphene to enhance the performance of terahertz metamaterial absorbers. Silicon (Si) is often utilized as a dielectric spacer material due to its well-established compatibility with nanofabrication processes and its excellent dielectric properties.19,20 Gold (Au) is known for its outstanding electrical conduction and ease of processing and is often used as the metal layer in metamaterial designs mostly as the ground plane or for forming resonant structures. Combining graphene with silicon and gold effectively creates high-efficiency terahertz absorbers with strong multi-band performance.21,22 Researchers have also discovered the use of materials such as aluminum (Al), silver (Ag) and copper (Cu) in their designs where each element has specific advantages depending on the desired outcome of the absorber. For example, aluminum is frequently used due to its low cost and ease of fabrication while silver is valued for its high conductivity.23,24 Furthermore, materials like GaAs and silicon dioxide (silica) have been commonly used as substrates to provide excellent dielectric properties which confirms the stable and effective performance of the absorber. GaAs, with its high refractive index and strong compatibility with graphene, enhances the coupling between the graphene layers and the incident terahertz radiation and improves the absorption efficiency.25,26 Silica on the other hand is often utilized for its transparency to terahertz waves and favorable dielectric constant which aids in upholding the performance of the absorber while also ensuring structural stability.27,28 Metamaterial absorbers composed of graphene and these matching materials have demonstrated the ability to achieve high absorption efficiencies across a broad range of terahertz frequencies.29 These designs are vital for widespread applications in terahertz technologies where operating in a broad frequency range is often required. Moreover, these absorbers also exhibit polarization insensitivity which is a highly required feature in many practical applications as it allows for reliable performance regardless of the angle or polarization of the incoming terahertz radiation.30,31 Recently complex, multi-layer structures stacked on one another to create terahertz absorbers were developed and used. These hybrid materials provide a wide range of tunable electronic and optical properties that can be used to achieve greater flexibility and performance in terahertz absorption.32 By merging materials with matching property elements such as the high electrical conductivity of graphene with the strong dielectric properties of silicon, researchers are able to create absorbers with extraordinary performance that include high efficiency, tunability and broad bandwidths.33
In this paper, we present a novel design for a tunable terahertz absorber that structures a two-layer design that joins the tunable properties of graphene to achieve broadband, multi-peak absorption across the terahertz spectrum. The design consists of a gold base layer, a GaAs dielectric spacer and a graphene layer placed at the center of the unit cell from bottom to top. This is added by a second GaAs spacer and four graphene patches at the corners of the unit cell which further improve the interaction between terahertz radiation and the absorber. The ability to precisely tune the absorption peaks by controlling the chemical potential of graphene offers high flexibility and efficiency in controlling the absorption performance at specific terahertz frequencies. The key feature of this design is its ability to generate eight sharp absorption peaks spanning from 3.9 THz to 9.73 THz with seven peaks exceeding 99.9% absorption efficiency and one peak at 97.4% absorption and therefore resulting in a total absorption average of 99.3%. These absorption peaks occur at frequencies of 3.9 THz, 4.67 THz, 5.5 THz, 6.35 THz, 7.2 THz, 8.05 THz, 8.9 THz and 9.73 THz. The precise tuning of these peaks is accomplished by regulating the Fermi level (Ef) of the graphene which permits selective absorption at various frequencies. This high level of accuracy makes the design suitable for applications requiring fine control over frequency selection.
Simulation results reveal that the key parameters such as the Fermi level of graphene, relaxation time, graphene temperature and arrangement of the graphene patches significantly affect the absorption performance. Detailed parametric analyses show that the Fermi level directly affects the placement and sharpness of the absorption peaks that allow fine-tuning of the design. The relaxation time also influences the rate at which the graphene's surface conductivity adjusts to the Terahertz field which enhances the efficiency of the absorber. The electric field distribution within the structure demonstrates the resonant modes shaped by the graphene patches which confirms the effective interaction between the terahertz waves and the absorber's material. The high efficiency multi-peak absorption design we proposed delivers a multipurpose solution for broadly applicable terahertz technologies that include medical diagnostics, material analysis, security screening and non-destructive testing.34,35 The key innovations in our design include its simple and scalable configuration which reduces fabrication complexity while maintaining high efficiency. The design achieves eight precisely almost equidistant absorption peaks and offers tunability across a wider bandwidth than previously reported absorbers. This unique arrangement is particularly suited for applications requiring selective frequency absorption and fine-tuned resonance such as early cancer detection, material characterization and public safety screening.
δ = 0.006 allows efficient impedance matching and reduces energy losses during the propagation of terahertz waves through the structure.
The central graphene layer which is placed above the GaAs spacer is the active material responsible for tuning the absorption. The graphene layer with a thickness of 1 nm has the unique ability to modulate its surface conductivity and Fermi level through an external voltage. This allows the tunable absorption that defines the performance of the absorber. With a relaxation time of τ = 0.1 ps, a chemical potential of 1.5 eV and a temperature of 300 K, graphene can be adjusted to selectively absorb terahertz radiation at specific frequencies which provides flexibility and precision in applications requiring dynamic frequency tuning.
Sitting on top of the central graphene layer is another GaAs dielectric spacer. This second GaAs spacer is 5 μm thick which isolates the graphene patches positioned at the corners of the unit cell from the central graphene layer. All graphene patches are 15 μm × 15 μm wide and introduce additional resonant modes that allow multi-band absorption at different terahertz frequencies. The patches further enhance the sharpness and definition of the absorption peaks which improves the overall performance of the absorber. The strategic positioning of these patches at the top corners ensures that they interact with the incident terahertz waves independently and promote multi-frequency absorption.
In Fig. 1(a) the perspective view of the unit cell is presented which provides an overview of the entire structure from the gold base layer to the graphene patches. Fig. 1(b) illustrates the layer-by-layer breakdown of the structure showing the thickness and positioning of each layer including the gold base, GaAs spacers, central graphene layer and the top graphene patches. The preparation process of the dual-layer graphene metasurface absorber is detailed in Fig. 2. Initially, the dielectric structure is deposited onto the metallic base (Au) using physical vapor deposition (PVD) to ensure a stable foundation. For the graphene sheet, graphene is synthesized via chemical vapor deposition (CVD) on a copper catalyst. The isolation layer is then transferred onto the GaAs dielectric spacer using a wet transfer method which ensures minimal defects and maintains the graphene's electronic properties. To realize the precise dual-layer patterned graphene configuration, electron beam lithography (EBL) is employed which is followed by oxygen plasma etching (OPE) to remove any undesired portions and achieve the desired geometric pattern.36 Finally, the photoresist is stripped, resulting in the dual-layer graphene metasurface absorber design ready for use in terahertz applications.
To analyze and optimize the proposed metasurface absorber, simulations were performed using CST Studio Suite 2019 which is a commercially available electromagnetic simulation software. Periodic boundary conditions were applied along the x and y directions to ensure the periodicity of the metasurface design while an open boundary condition was set along the z direction to permit wave propagation. A plane wave was incident from the negative z direction with the electric field polarized along the y-axis to certify precise simulation of electromagnetic interactions. For high precision and accuracy, a fine-tuned tetrahedral mesh was employed with 178
778 elements. Careful adjustments were made to accurately model the unique properties of the graphene layer and the geometric dimensions of the unit cell were meticulously optimized to achieve multi-peak absorption across the terahertz range. The design stands out by combining simplicity with scalability. In other words, it offers a structure that is easier to fabricate compared to the intricate patterns used in many existing designs while achieving an unprecedented bandwidth of 3.9–9.73 THz with eight distinct absorption peaks.
| σ(ω) = σinter(ω) + σintra(ω) | (1) |
![]() | (2) |
![]() | (3) |
![]() | (4) |
This conductivity formula governs the interaction of graphene with the incident terahertz waves and defines the resonance condition of the absorber. The multi-peak absorption behavior observed in the design results is formed due to the excitation of multiple resonant modes within the unit cell of the metamaterial. Each resonant mode corresponds to a distinct absorption peak in the terahertz spectrum. The precise frequency of each peak is influenced by the size and placement of the graphene patches as well as the dielectric constant of the spacer material. By tuning the chemical potential ‘Ef’ of graphene the resonant frequencies can be adjusted which allows dynamic control over the absorption peaks. The sharpness of these peaks is influenced by the relaxation time ‘τ’. With shorter relaxation times, reducing the coupling between the incident waves and the graphene layer leads to sharper and more distinct absorption peaks.
Moreover, the absorption efficiency A(ω) of the proposed terahertz metasurface absorber can be calculated using its S-parameters which describe the transmission and reflection characteristics of the absorber at a given frequency. The absorption efficiency is expressed as:40
| A(ω) = 1 − T(ω) − R(ω) = 1 − S212 – S112 | (5) |
| A(ω) = 1 − R(ω) = 1 – S112 | (6) |
Fig. 4(b)–(d) provide a detailed view of selected absorption peaks and focus on regions where absorption efficiency exceeds 80%. Fig. 4(b) zooms in on the absorption peak near 6.347 THz. At 1.5 eV, the maximum absorption occurs at 6.347 THz, whereas for 1 eV and 2 eV the peaks shift to 6.321 THz and 6.372 THz respectively. Similarly, Fig. 4(c) highlights the absorption peak near 7.2 THz. The peak for 1.5 eV is located at 7.205 THz while the peaks for 1 eV and 2 eV occur at 7.172 THz and 7.231 THz respectively further demonstrating the forward movement of the peaks with increasing eV. Fig. 4(d) focuses on the peak near 8.056 THz where the maximum absorption for 1.5 eV is at 8.056 THz for 1 eV at 8.0175 THz and for 2 eV at 8.089 THz. These observations consistently show that higher chemical potential values result in absorption peaks shifting to higher frequencies. This high degree of tunability demonstrates the potential of the proposed metasurface absorber for applications requiring adaptive resonance frequencies. For instance, in Fig. 4(b), the tunability enables fine control within a narrow band near 6.35 THz while in Fig. 4(c) and (d) the absorber achieves similar control in the 7.2 THz and 8.05 THz regions, respectively.
Fig. 5 illustrates the effect of relaxation time (τ) and operating temperature on the absorption spectrum of the proposed metasurface absorber. In Fig. 5(a), the absorption performance is analyzed for three relaxation time values i.e., 0.1 ps, 0.3 ps, and 0.5 ps. It is observed that as τ increases, there is a slight reduction in absorption efficiency especially at lower frequencies. Although the absorption remains above 90% even at τ = 0.5 ps, a minor redshift in the resonance peaks is observed with increasing τ which is attributed to reduced coupling efficiency between the terahertz waves and the graphene surface. The highest absorption and sharpest peaks occur at τ = 0.1 ps which makes it the optimal choice for this design to achieve superior performance in the desired frequency range. Fig. 5(b) examines the absorption spectrum at different operating temperatures i.e., 275 K, 300 K and 325 K. The results reveal that variations in temperature have a negligible impact on the absorption characteristics with the resonance frequencies and peak efficiencies remaining nearly identical across all temperatures. This temperature insensitivity underscores the robustness of the metasurface absorber which ensures stable performance under varying environmental conditions. Such stability is particularly advantageous for practical applications that require consistent absorption efficiency in dynamic thermal environments.
The size of the top graphene patch (a) plays a pivotal role in defining the resonant behavior and absorption efficiency of the metasurface absorber. As shown in Fig. 6, the absorption spectrum is highly dependent on ‘a’ with the highest absorption achieved for a = 15
μm. The results demonstrate that as ‘a’ decreases particularly below 7 μm, there is a noticeable reduction in absorption efficiency most significantly at lower frequencies. This occurs because the patch size directly influences the inductive and capacitive properties of the resonant structure which in turn determine the resonance frequency and coupling strength between the incident terahertz waves and the metasurface. Smaller patch sizes reduce the effective interaction area for the incident radiation hence weakening the resonance modes and leading to diminished absorption. Conversely, larger patch sizes provide stronger electromagnetic coupling and better confinement of the THz waves within the structure which results in sharper and more efficient absorption peaks.
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Fig. 6 Absorption spectrum vs. patch size ‘a’ and the frequency showing maximum absorption at a = 15 μm and reduced efficiency as ‘a’ decreases. | ||
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| Fig. 7 (a) Absorption remains above 95% for incidence angles θ from 0° to 50°. (b) Polarization insensitivity is observed for angles ϕ from 0° to 90°. | ||
The combined effects of angular stability and polarization insensitivity make the proposed metasurface absorber a highly steadfast structure under varying operative parameters. The preservation of high absorption efficiencies at oblique incidence angles and across all polarization states validates the capability of the design to maintain its resonant behavior and absorption efficiency under challenging conditions. These results reflect the absorber's well-engineered structural and material properties which are augmented to provide consistent interaction with terahertz waves regardless of variations in incidence angles or polarization.
The electric field (E-field) distribution plays an important role in understanding the resonance mechanisms and performance of the proposed metasurface absorber. Investigating the E-field at various points across the spectrum provides insights into how the absorber interacts with incident electromagnetic waves to achieve high absorption efficiency. The E-field intensity directly links with the resonance behavior which affects the sharpness and efficiency of absorption peaks. Fig. 8 highlights the E-field distribution at specific resonance peaks and their corresponding dips. Fig. 8(a–d) shows the E-field distribution at the absorption peaks of 3.9 THz, 4.67 THz, 6.35 THz and 9.73 respectively. At these frequencies the E-field is highly contained and intense near the edges of the graphene patches and the surrounding dielectric material. This strong localization signifies efficient coupling between the incident terahertz waves and the resonant modes of the metamaterial which leads to maximum absorption. The sharp intensity gradients observed emphasize the high Q-factor and narrow full-width at half maximum (FWHM) achieved by the design.
Conversely, panels Fig. 8(e–h) illustrate the E-field distribution at the dips immediately following these peaks, at 4.4 THz, 5.15 THz, 4.7 THz and 10 THz respectively. At these dips, the E-field intensity is substantially reduced which indicates weaker interaction between the electromagnetic waves and the absorber structure. This reduction in E-field strength corresponds to the minima in the absorption spectrum that highlights the design's sharp resonance and high selectivity. The contrasting E-field patterns between the peaks and dips underscore the absorber's ability to effectively manipulate electromagnetic energy at targeted frequencies.
Table 1 shows a comparison of the proposed terahertz absorber with several state-of-the-art designs. The proposed absorber achieves eight distinct absorption peaks across a broad frequency range of 3.9 to 9.73 THz. With an impressive 99.3% average absorption it proposes superior efficiency compared to many existing designs. The absorber also maintains angular stability from 0° to 50°. Notably, the design provides precise tuning down to very small scales and displays a total polarization insensitivity of up to 90°. These features combined with the broad frequency range and high absorption efficiency make our design a noteworthy advancement over current absorber technologies. The combination of these features i.e., broad frequency coverage, exceptional absorption efficiency, angular stability, precise tunability and polarization insensitivity positions our design as a significant advancement over current terahertz absorber technologies. This innovative design addresses key challenges in the field and provides a robust solution for a wide range of applications including sensing, imaging and material characterization.
| Ref. | Frequency (THz) | No. of peaks | Absorption average (%) | Angular stability | Polarization insenstivity | Tunable | Year published |
|---|---|---|---|---|---|---|---|
| 41 | 1.6, 4.42, and 4.94 | 3 | 99 | 0–60 | Yes | No | 2018 |
| 42 | 0.85 and 3.37 | 2 | 95.1 | 0–80 | Yes | Yes | 2018 |
| 43 | 7.75, 14.85, and 23.43 | 3 | 99 | 0–40 | Yes | Yes | 2019 |
| 44 | 0.114 and 0.181 | 2 | 98.9 | 0–45 | Yes | No | 2020 |
| 45 | 0.33, 0.90, 1.42, and 1.85 | 4 | 99 | 0–60 | Yes | No | 2021 |
| 46 | 1.36, 2.6, 3.68, and 4.36 | 4 | 98.2 | 0–45 | Yes | No | 2022 |
| 47 | 1.7, 2.8, 3.2, and 3.5 | 4 | 99.1 | — | Yes | No | 2023 |
| 48 | 0.865, 1.43, and 2 | 3 | 99.5 | 0–45 | Yes | Yes | 2024 |
| 49 | 1.99, 6, 7.37, 8.47, and 9.38 | 5 | 97.9 | 0–50 | Yes | Yes | 2024 |
| This work | 3.9, 4.67, 5.5, 6.35, 7.2, 8.05, 8.9, and 9.73 | 8 | 99.3 | 0–50 | Yes | Yes | — |
| This journal is © The Royal Society of Chemistry 2025 |