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Correction: Isomerisation of phosphabutyne and a photochemical route to phosphabutadiyne (HC3P), a phosphorus analogue of cyanoacetylene

Arun-Libertsen Lawzer *a, Elavenil Ganesan a, Thomas Custer a, Jean-Claude Guillemin b and Robert Kołos a
aInstitute of Physical Chemistry, Polish Academy of Sciences, Ul. Marcina Kasprzaka 44/52, 01-224, Warsaw, Poland. E-mail: alawzer@ichf.edu.pl; eganesan@ichf.edu.pl; tcuster@ichf.edu.pl; rkolos@ichf.edu.pl
bUniversity of Rennes, Ecole Nationale Superieure de Chimie de Rennes, CNRS-IRCR, 6226, F-35000, Rennes, France. E-mail: jean-claude.guillemin@ensc-rennes.fr

Received 24th March 2025 , Accepted 24th March 2025

First published on 31st March 2025


Abstract

Correction for ‘Isomerisation of phosphabutyne and a photochemical route to phosphabutadiyne (HC3P), a phosphorus analogue of cyanoacetylene’ by Arun-Libertsen Lawzer et al., Phys. Chem. Chem. Phys., 2025, https://doi.org/10.1039/d4cp04182h.


The authors would like to correct an error in Scheme 2 of the published article. Relative energy values in the published version of Scheme 2 incorrectly account for zero-point energy. Correct values are shown here. These changes do not affect the conclusions or text of the original article:
image file: d5cp90069g-s2.tif
Scheme 2 Products formed in the 254 nm photolysis of phosphabutyne in solid argon. The placement of the arrows, while compatible with Fig. 1 and 7, is provisional. DFT-derived relative electronic energies of the isomers of C3H5P species are provided.

The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.


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