Ningning
Yu‡
a,
Wenyu
Chen‡
a,
Mengyuan
Li‡
a,
Yingru
Lin
a,
Xinyu
Du
a,
Yingying
Zheng
a,
Jing
Yang
a,
Wenxin
Huang
a,
Zhiqiang
Zhuo
a,
Chuanxin
Wei
b,
Xiang
An
a,
Yamin
Han
*a,
Lubing
Bai
a,
Jiewei
Li
a,
Xuehua
Ding
a,
Heyuan
Liu
*c,
Man
Xu
b,
Wei
Huang
ab and
Jinyi
Lin
*a
aKey Laboratory of Flexible Electronics (KLoFE) and Institute of Advanced Materials (IAM) Nanjing Tech University (Nanjing Tech), 30 South Puzhu Road, Nanjing 211816, China. E-mail: iamjylin@njtech.edu.cn; liuheyuan123@upc.edu.cn; iamymhan@njtech.edu.cn
bState Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China
cSchool of Materials Science and Engineering, Institute of New Energy, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, China
First published on 13th June 2024
Multiple-site functionalization of deep-blue light-emitting conjugated molecules can not only optimize photo-electrical processing to obtain robust electroluminescent behavior but also enhance the film-forming ability to manufacture large-area film via solution processing technology. Herein, we demonstrate a pendant side-functionalization to prepare a series of unsymmetrical substituted steric terfluorenes (MC8 and MC6Cz) via originally introducing the alkoxy and carbazole group at the 4-position of fluorene segments for the narrowband ultra-deep-blue solution-processed organic light-emitting diodes (OLEDs). Both materials exhibited an ultra-deep-blue emission with CIE coordinates of (0.16, 0.06) and PLQY efficiencies of ∼60% due to the single-molecular exciton behavior without polariton formation, confirmed by the time-resolved transient spectroscopy. Interestingly, compared to the MC8, MC6Cz films present stable deep-blue emission without obvious green-band emission when thermally annealed in the air or irradiated for 3 hours under UV light, attributed to the self-encapsulation of the pendant carbazole group. Finally, MC6Cz-based OLEDs exhibited a narrowband ultra-deep-blue emission, a high brightness at low current density, with a high external quantum efficiency (EQE) of 1.17% and CIE coordinates of (0.16, 0.06). All the above results confirm that the introduction of the Cz group inhibits the aggregation between molecular main chains, realizing the single molecular mechanism of exciton behavior, establishing the two-dimensional carrier transport channel, and improving the morphology, spectral stability and efficiency of the material, which are conducive to the realization of efficient and stable solution-processed deep-blue light-emitting devices.
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Scheme 1 Molecular design principle of unsymmetrical substituted steric terfluorenes via pendant side-functionalization. (a) Energy level diagram of traditional OLED based on terfluorenes.11,29 (b) Undesirable energy transfer from wide bandgap emission center to narrowband defect structure, which results in a low efficiency and color purity of deep-blue emission.30 (c) To suppress the formation of the charge transfer (CT) state can reduce the structural distortion and present a narrowband emission. The introduction of steric hindrance groups inhibits molecular aggregation and induces narrowband emission.31 (d) Different pendants of steric terfluorenes. Schematic diagram of unsymmetrical substitution of steric terfluorenes via carbazole pendant functionalization at 4-position. (e) Efficient intermolecular charge transport in the Cz pendant functionalized terfluorene. The pendant Cz group at the unsymmetrical 4-site substitution of fluorene monomers can act as a charge transport station to enhance the film conductivity, although there is an extremely weak intermolecular π interaction and electron coupling. |
Similar to the industrial pulse assembly lines, modular production of LCMs have a series of advantages, such as precisely tenable electronic structure, controllable structural modification, and low-cost manufacture, analogous to Lego.32,33 In general, LCMs consists of some typical conjugated segments, such as p- or n-type, and π-bridge units, that former two group can precisely tune the electronic structure and bangap to modulate the emission color and charge behavior, and the latter always control the intramolecular charge transfer and electron delocalization toward the optimization of the photophysical and electrical property.10,33 Up to date, a series of p- and π-bridge moieties, such as anthracene, pyrene, dimesitylborane and fluorene phenanthroimidazole, are developed to manufacture deep-blue fluorescent LCMs.10,25,29 Among them, fluorene is a common and universal segment to build high efficiency deep-blue LCM, due to its intrinsic multi-sites structural functionalization, wide bandgap and deep-blue emission for the light-emitting devices.10,29,33 However, the traditional fluorene-based derivatives always suffer from poor color purity and low efficiency of deep-blue emission, especially for the long-time aging and device operation. Defect structures, such as fluorenone and excimer trapping sites, always caused long-wavelength emission and nonradiative processing, which are harmful to the efficiency, color purity and stability of deep-blue OLEDs.30,34 Besides, the unmatched energy level for the fluorene-based OLEDs also cause a serious and bad carrier injection, due to the intrinsic wide bandgap of homo-fluorene with a low highest occupied molecular orbital (HOMO), which also result in a charge accumulation for the large hole-injection barrier, which may also result in a low operation lifetime (Scheme 1).11,29 To resolve these problems, herein, we demonstrated two novel terfluorenes to explore the role of charge-transport pendant segment (MC6Cz and MC8), carbazole (Cz), on the stability and efficiency of the deep-blue solution-processed OLEDs. As we expected, MC6Cz and MC8 spin-coated films showed deep-blue emission with a PLQY of ∼60%. More interestingly, compared to MC8 ones, MC6Cz spin-coated films show a relatively stable and narrowband deep-blue emission without obvious green-band emission after keeping it in air atmosphere (∼3 h). OLEDs based on the MC6Cz had a maximum external quantum efficiency (EQE) of 1.17% and CIE coordinates of (0.16, 0.06). Furthermore, MC6Cz-based OLEDs also had a longer operation lifetime and stable color purity stability than those of MC8, revealing that the introduction of the pendant Cz segment is useful to improve the efficiency and operation lifetime of deep-blue OLEDs.
Firstly, the photophysical behaviour of the two compounds in solution and the thin film was further investigated, including techniques such as steady UV-vis absorption, PL spectra, time-resolved fluorescence emission decays spectra and transient absorption (TA) analysis. As displayed in Fig. 1a and b, for the absorption spectra of a dilute solution, MC8 has an absorption peak at 360 nm, and MC6Cz has two absorption peaks at 348 nm and 360 nm. The former absorption peak for MC6Cz is attributed to the carbazole. For the PL spectra of the dilute solution, the two materials have three emission peaks with the same characteristics at 405 nm, 428 nm, and 460 nm, due to the singlet transition within the chromophore 0–0, 0–1, 0–2 of the conjugated structure. The absorption spectra of the two materials' spin-coated films are similar to those of the dilute solution, indicating no significant molecular aggregation behaviour in the film.16,30 Compared with the dilute solution, the PL spectra of the spin-coated films have a smaller red-shift, attributed to the constraints of intramolecular conformational motion. Meanwhile, the emission peaks of MC8 spin-coated film are at 410 nm, 434 nm, 465 nm, and those of MC6Cz films are estimated at 415 nm, 437 nm, and 470 nm, consistent with the corresponding PL-mapping plots in Fig. S8 (ESI†). Correspondingly, the CIE coordinates of both materials are about (0.16, 0.06). The results show that it has excellent ultra-deep-blue emission behaviour and can be used in the field of information display. In addition, the lifetime and fluorescence quantum efficiency of the two material films were studied by time-resolved transient PL measurements. The lifetimes of MC8 and MC6Cz were calculated as 0.49 ns and 0.50 ns (Fig. S9, ESI†). More importantly, the fluorescence quantum efficiency of MC8 and MC6Cz were estimated to be 51.27% and 59.51%, also revealing a robust deep-blue emission. Their radiative and non-radiative transition rates were calculated, as shown in Fig. 1c and d. A higher radiative transition rate and a lower non-radiative transition rate of MC6Cz, indicate that the carbazole group effectively inhibits the non-radiative transition of excitons and improves excitons utilization, which also reasonably explains the higher fluorescence quantum efficiency of MC6Cz than those of MC8.
In order to research the film formation of these compounds, the spin-coated films were subjected to XRD morphological characterization. Both of the spin-coated films exhibit relatively wide random scattering peaks (Fig. S11, ESI†), suggesting the amorphous states in the solid films. To further investigate the emission spectral stability, the thermal annealing and aging treatments of their spin-coated films were subjected to both materials. Spin-coated film was thermally annealed at 120 °C in the air for different times (Fig. S10, ESI†), no significant changes in the PL spectra were observed at different annealing times, and no green light band at 500–550 nm were discovered for their annealed films, evidencing that two materials have good deep-blue PL spectral stability. Then, the spin-coated films of the two materials were also exposed to a 365 nm UV lamp for 3 h for the continuous aging experiment. Surprisingly, a clear peak at 550 nm appeared for the MC8 aged films at 1.5 hours of continuous irradiation under a UV lamp, while there is no obvious green-band emission for MC6Cz even at 3 hours of irradiation, also effectively suggesting that the suppression of green-band emission by pendant carbazole units (Fig. 1e and f). What is more, as can be seen from the photographs that the colour of the MC8 film changes significantly under UV lamp irradiation, to blue-green emission after 2.0 hours, while the MC6Cz film has a slight change in colour, remaining pure blue emission after 3 h. From the above results, compared to MC8, MC6Cz presents excellent deep-blue spectral stability. In summary, the introduction of Cz groups, steric hindrance functionalization of the fluorene main chain, barrier layer in the conjugated main chain, reduced Stokes shift, enabling the molecular level coating of luminous color groups and inhibiting the aggregation between molecular main chains, realizes the exciton behavior of single molecule mechanism and improve the morphological and spectral stability of the film. At the same time, the non-radiative transition of excitons can be effectively inhibited, the utilization rate of excitons can be improved, and the generation of the green band can be inhibited, which is conducive to the realization of efficient and stable solution-processable deep-blue light-emitting devices.
The intermolecular interaction and aggregation always affect the dynamical behavior of excited states and excitons. We further investigated the behaviour of excitons in films of MC6Cz and MC8 by femtosecond transient absorption spectroscopy. Fig. 2a and b show TA contour plots of the two types of spin-coated films in the 350 to 750 nm. Both contour plots consist of three distinct regions, where the positive signal in the 350–410 nm spectral range (red region) shows photobleaching (PB), consistent with the absorption spectra of the film. The 410–480 nm spectral range (red region) is attributed to stimulated emission (SE), consistent with the emission spectra of the films. The negative signal at long wavelengths (blue region) is associated with photoinduced absorption (PA). The differential transmission (ΔT/T) spectra of two material spin-coated films at the probe delay time are in Fig. 2c and d. The spectra of the two materials showed similar trends over the entire time scale. The PB and PA signals of MC6Cz are both stronger than MC8, indicating that the excited state excitons of MC6Cz are reabsorbed, which improves the utilization rate of the exciton. In addition, the ΔT/T zero-crossing point of MC6Cz is red-shifted relative to MC8, indicating that the formation of polariton pairs in MC6Cz is effectively suppressed, showing single-molecule emission, which explains the low non-radiative transition of MC6Cz. Furthermore, the SE and PA kinetic traces (Fig. S12, ESI†) have perfect symmetric ΔT/T behaviour, further confirming their single-molecule exciton emission in the film.
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Fig. 2 Transient absorption (TA) analysis of MC8 and MC6Cz films. TA contour plots of MC8 (a) and MC6Cz (b). (c) and (d) ΔT/T spectra of MC8 and MC6Cz films from 0.5 to 5.0 ps pump–probe delay. |
To obtain a deep understanding of this pendant functionalization on the electronic structure, we also performed DFT calculations of both compounds and obtained the optimized structure and the molecular orbitals of the highest occupied (HOMO) and lowest unoccupied (LUMO), as shown in Fig. S13 (ESI†). The large dihedral angle between diphenyls at the 9 positions of the fluorene, and this structure is effective in reducing aggregation caused by intermolecular interactions, which is conducive to improving deep-blue emission and their stability. In addition, it also concluded that the pendant Cz group is slightly influenced by the photophysical processing of the terfluorene backbone structures, which is beneficial for obtaining single-chromophore emission behavior. Besides, the calculated HOMO and LUMO energy levels of the MC8 and MC6Cz are −5.14 eV and −1.45 eV, −5.25 eV and −1.54 eV, respectively, indicating the narrow energy gaps for deep-blue emission. The electrochemical properties of the materials were characterized by CV (Fig. S14, ESI†). The HOMO and LUMO of the materials were calculated from HOMO/LUMO = −[Eonset – E(Fc/Fc+) + 4.8] eV. The onset of the oxidation potential (Eox) for MC8 and MC6Cz are 1.46 eV and 1.14 eV, and their onset of reduction potential (Ered) are −1.85 eV and −1.93 eV, respectively. As a result, the HOMO and LUMO energy levels for MC8 and MC6Cz are −5.79 eV and −2.48 eV, −5.48 eV and −2.40 eV, respectively. Therefore, the introduction of the pendant Cz units can increase the HOMO energy level to ensure the hole injection from the hole-transporting layer (HTL, such as PEDOT: PSS) and avoid charge accumulation (as shown in Scheme 1a), effectively improving the efficiency and stability of OLEDs.
The stability of the thin film morphology is very important for the fabrication and performance of the device, so the spin-coated films were subjected to FLM and AFM morphological characterization. As shown in Fig. 3e and g, both spin-coated films (40–50 nm) present smooth and particle-free surface morphology, with RMS roughness of 0.261 nm, and 0.302 nm for MC8 and MC6Cz, respectively. The roughness of MC6Cz is slightly higher than that of MC8, mainly due to the increased entanglement of the molecular chains by the Cz group. In addition, the surface morphologies of their annealed films were characterized by AFM measurements (Fig. 3f and h), and RMS was estimated to be about 0.276 nm, 0.332 nm of MC8 and MC6Cz annealed film. The roughness of the spin-coated films is slightly changed after thermal annealing, indicating that they have good film morphological stability. At the same time, the FLM images (Fig. 3a–d) of the pristine film as well as the annealed film of both materials also show smooth and particle-free surfaces, and the annealed films are intact without significant changes. Therefore, the two materials have good thin film morphology and stability, and have good ability to fabricate devices by solution processing. Due to their ultra-deep blue emission, excellent film morphology, good spectral stability, and excellent solubilizable properties, these two materials can be used as candidate emission materials for deep-blue solution-processed OLEDs. Subsequently, preliminary single-layer OLEDs are fabricated with a traditional configuration of ITO/PEDOT:PSS (40 nm)/emission layer (EML, 45 nm)/TPBi (20 nm)/LiF (1 nm)/Al (100 nm), as shown in Fig. 4a. As expected, EL spectra of OLEDs based on MC8 and MC6Cz consisted of 410 nm and 434 nm, 415 nm and 437 nm, respectively, similar to their PL spectra, as shown in Fig. 4b and c, indicating extremely weak interchain aggregation. More importantly, both two OLEDs exhibited narrowband deep-blue emission with an FWHM of <50 nm. Besides, with the increase of applied voltage, in contrast to MC8 ones, OLEDs based on MC6Cz exhibit a stable EL spectral profile without an obvious emission peak at 500–600 nm, confirming the good deep-blue emission spectral stability. Corresponding CIE values of the MC8 and MC6Cz (Fig. 4d) are (0.17, 0.07) and (0.16, 0.06), respectively, suggesting the ultra-deep blue emission. As shown in Fig. 4e, current efficiency versus luminance curves, the maximum external quantum efficiency (EQE) values of MC8 and MC6Cz were estimated at about 0.76% and 1.17%, respectively. As we expected, MC6Cz has a relatively high EQE, indicating that the carbazole group improves the carrier mobility of the materials. Meanwhile, the turn-on voltages of MC8 and MC6Cz are estimated at about 5.0 V and 4.2 V respectively (Fig. 4f), indicating a better charge injection and high conductivity of the MC6Cz emission layers. Besides, the maximum luminance of MC8 and MC6Cz is about 959 cd m−2 and 667 cd m−2, respectively. More interestingly, MC6Cz-based OLED presents a high brightness at low current densities, attributed to the hole transport properties and matched energy level of carbazole. In addition, the MC6Cz-based OLEDs also have a longer operation time and stable color purity than those of MC8 (Fig. S16, ESI†), which also reveals that the introduction of a pendant Cz segment improves the efficiency and operation stability of deep-blue OLEDs. Because the Cz side group substituents can form an ordered stacked structure and form a new carrier transport channel, which can effectively improve the carrier transport characteristics and has important significance for improving the performance and efficiency of the device. Meanwhile, the relatively high and stable deep-blue emissions of MC6Cz in the coated films are also good for improving the device efficiency of OLEDs.
Footnotes |
† Electronic supplementary information (ESI) available. See DOI: https://doi.org/10.1039/d4qm00332b |
‡ Ninging Yu, Wenyu Chen and Mengyuan Li are contributed equally to this work. |
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