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Correction: Dearomatization of benzopyrylium triflates with sulfoxonium ylides

Alexandria N. Leveille , Marissa M. Allegrezza , Kalen Laybourn and Anita E. Mattson *
Department of Chemistry and Biochemistry, Worcester Polytechnic Institute, 100 Institute Road, Worcester, MA 01609, USA. E-mail: aemattson@wpi.edu

Received 11th January 2023 , Accepted 11th January 2023

First published on 18th January 2023


Abstract

Correction for ‘Dearomatization of benzopyrylium triflates with sulfoxonium ylides’ by Alexandria N. Leveille et al., Chem. Commun., 2022, 58, 12600–12603, https://doi.org/10.1039/D2CC02023H.


The authors regret that the original article included minor errors in the sulfoxonium ylide structure shown in Schemes 2 and 3, and in Table 4, and in compound 3f shown in Table 1. The corrected schemes and tables are presented here.
image file: d3cc90024j-s2.tif
Scheme 2 Ring expansion of benzopyrylium ions generated in situ to access benzoxepines.

image file: d3cc90024j-s3.tif
Scheme 3 Plausible reaction pathway for enantioselective cyclopropanation and ring-opening sequence.
Table 1 Substrate screen based on sulfoxonium ylides
image file: d3cc90024j-u1.tif


Table 4 Influence of anion-binding catalysts on enantiocontrol
image file: d3cc90024j-u2.tif


The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.


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