Linchao Zeng‡
ab,
Jianhui Zhu‡ac,
Minsu Liub and
Peixin Zhang
*a
aCollege of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, P. R. China. E-mail: pxzhang@szu.edu.cn
bShenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute, Tsinghua University, Shenzhen 518055, P. R. China
cCollege of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an, Shannxi 710055, P. R. China
First published on 10th February 2021
An air-stable antimony (Sb) nanosheet modified separator (SbNs/separator) has been prepared by coating exfoliated Sb nanosheets (SbNs) successfully onto a pristine separator through a vacuum infiltration method. The as-prepared Li–S batteries using SbNs/separators exhibit much improved electrochemical performance compared to the ones using commercial separators. The coulombic efficiency (CE) of the Li–S battery using the SbNs/separator after the initial cycle is close to 100% at a current density of 0.1 A g−1, and 660 mA h g−1 capacity retained after 100 cycles. The rate capability of Li–S battery using SbNs/separator delivers a reversible capacity of 425 mA h g−1 when the current density increases to 1 A g−1. The improved electrochemical performance is mainly attributed to the following reasons. Firstly, the combination of physical adsorption and chemical bonding between SbNs and lithium polysulfides (LiPSs), which efficiently inhibits the shuttle phenomena of LiPSs. Secondly, the good electronic conductivity of SbNs improves the utilization of the adsorbed LiPSs, which benefits the capacity release of active materials. Lastly, the fast conversion kinetics of intermediate LiPSs caused by the catalytic effect from SbNs further suppresses the shuttle effect of LiPSs. The SbNs/separators exhibit a great potential for the future high-performance Li–S batteries.
Another possible strategy is to use carbonaceous conductive trap layers for LiPSs, which have been proven effective to solve both problems simultaneously.28–31 In these cases, the carbonaceous conductive interlayers adsorb the dissolved LiPSs physically and provide a transfer pathway for electrons to reactivate the adsorbed LiPSs. However, carbonaceous material can only provide weak interaction with LiPSs due to the physical adsorption mechanism, which cannot effectively inhibit the shuttle phenomena of LiPSs. The phosphorene exfoliated from black-phosphorus (BP) is considered as a promising candidate material for trap layer in LiPSs, based on its high physical and chemical adsorption ability and high electron conductivity (∼300 S m−1).32,33 Consequently, the prepared Li–S battery exhibits a stable cycle performance of 780 mA h g−1 after 100 cycles at 0.4 A g−1 and an outstanding rate performance of 600 mA h g−1 at 3.5 A g−1.34 However, the practical applications of phosphorene is still hindered by its poor stability at ambient environment.35 It is an urgent task to develop a suitable trap layer material that possesses simultaneously high electron conductivity, high adsorption ability for LiPSs, and high ambient stability.
Metallic antimony with gray allotrope (Sb, R3m space group), an element in the same group as phosphorus, is also a layered material consisting of fused, ruffled, six-membered rings, which may be promising to construct a trap layer for LiPSs. Firstly, Sb is stable in the ambient environment, which can be exfoliated through the widely used sonication process for preparing SbNs efficiently.36–38 Secondly, SbNs exhibit outstanding electron conductivity of ∼1.6 × 104 S m−1 for fast electron transfer.39–41 Thirdly, the diffusion energy barrier for Li atom within SbNs is only ∼0.48 eV, which benefits the transfer of Li+ within SbNs material.42 Lastly a stable chemical bonding can be formed between Sb atom and S atom, which will facilitate the adsorption of LiPSs to Sb material.43
In this work, we developed an-air stable SbNs-modified separator for Li–S batteries with excellent electrochemical performance. This was fulfilled by firstly fabricating SbNs by a sonication-assisted liquid exfoliation method. Modified separator (SbNs/separator) was then prepared by coating the exfoliated SbNs onto a commercial separator using the vacuum filtration method. The chemical interaction between SbNs and LiPSs was revealed. Compared with the Li–S batteries using commercial separators, the ones using as-prepared SbNs/separators exhibit superior electrochemical performance. When cycled at 0.1 A g−1, the coulombic efficiency (CE) of Li–S battery using SbNs/separator after the initial cycle is close to 100% and the capacity retains 660 mA h g−1 after 100 cycles. The rate capability of Li–S battery using SbNs/separator is also excellent, delivering a reversible capacity of 425 mA h g−1 at a high current density of 1 A g−1. The improved electrochemical performance is mainly attributed to the combination of physical adsorption and chemical bonding between SbNs and LiPSs that efficiently inhibits the shuttle phenomena of LiPSs. Besides, the fast conversion kinetics of intermediate LiPSs caused by the catalytic effect from SbNs further suppresses the shuttle effect of LiPSs. In addition, the as-prepared SbNs with relative good electronic conductivity facilitates the transfer of electrons to the adsorbed LiPSs. The method of modifying separator with air-stable SbNs holds a great promise for future high-performance Li–S batteries.
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Fig. 1 Schematic illustration of the synthesis process for SbNs/separator and its mechanism in inhibiting the shuttle phenomena of polysulfide. |
Fig. S3† shows the field-emission scanning electron microscopy (FESEM) image of pristine Sb powder. The pristine Sb powder shows a granular morphology with particle size ranging from several microns to tens of microns. Fig. 2A shows the FESEM image of the product after the probe ultrasonication process. The prepared product shows a lamellar morphology, which indicates the exfoliation phenomena of pristine Sb powder. The size of the exfoliated SbNs is about 500 nm. From the AFM image (Fig. 2B), we can see that the exfoliated SbNs shows a thickness of about 4–5 nm. Besides, the transverse size of the exfoliated SbNs is about 0.5 μm. The exfoliated sample was further characterized by transmission electron microscopy (TEM) and high-resolution transmission electron microscopy. The SbNs shows a very thin structure with a transverse size of about 0.5 μm (Fig. 2C), which is consistent with the FESEM and AFM results. From HRTEM image, the lattice fringes of the dominated (012) crystal plane of Sb with a d-spacing of 0.318 nm and the (006) crystal plane of Sb with a d-spacing of 0.200 nm can be seen clearly, which demonstrates the gray allotrope phase of Sb with a space group of R3m is not changed after exfoliation (Fig. 2D).
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Fig. 2 FESEM (A) and AFM (B) images of SbNs. TEM (C) and HRTEM (D) images of SbNs. (E) XRD patterns of the pristine Sb powder and the SbNs powder. (F) Sb 3d high-resolution XPS spectra of SbNs. |
Fig. 2E presents the XRD patterns of pristine Sb powder and SbNs. The pristine powder shows the standard Bragg diffraction peaks of gray Sb. After the exfoliation process, the diffraction peaks of SbNs remain in the same position, but the intensity of these peaks are decreased, especially for the peak of (003) crystal plane. The decreased intensity of the diffraction peaks of SbNs is due to a much thinner thickness of the SbNs compared with the pristine Sb powder, which indicates an exfoliation process occurred during the probe sonication process.36,44 Besides, no additional XRD diffraction peaks are existed in the exfoliated sample, indicating no side reaction has occurred during the probe ultrasonication process, which is consistent with the result of HRTEM. Fig. S4† shows the Raman spectra of the samples. It can be seen that the pristine powder exhibits the standard Raman characteristic peaks of Sb. After probe ultrasonication, the Raman peaks of SbNs remain at the same position with the intensity of these characteristic peaks becomes much weaker, further indicating the successful exfoliation of metallic Sb nanosheets. Fig. S5† shows the XPS of pristine Sb powder and SbNs. The XPS spectra disclosed the existence of the Sb element without any impurity in Sb powder and SbNs, indicating no side reactions occurred during the exfoliation process. Fig. 2F shows the Sb 3d high-resolution XPS spectra of SbNs. The high-resolution Sb 3d peaks can be further deconvoluted into two symmetric signals with binding energies of 540.2 and 537.8 eV that correspond to Sb 3d3/2 main peak and 3d3/2 satellite peak, respectively. The specific surface area of the pristine Sb powder and SbNs were analyzed by nitrogen Brunauer–Emmett–Teller (BET) adsorption measurements (Fig. S6†). The pristine Sb possesses a specific surface area of 0.19 m2 g−1. After the exfoliation process, the BET surface area of SbNs increased sharply to 11.19 m2 g−1, which is about 59 times higher than that of the pristine Sb powder. This change is ascribed to the larger surface area of 2D structured after the exfoliation process.
Fig. 3A shows the initial several cyclic voltammetry (CV) curves of Li–S battery using SbNs/separator in the potential range of 1.8–2.8 V. It exhibits two cathodic peaks (one at 2.27 V and the other at 1.94 V) in the 1st cathodic scan. The cathodic peaks at 2.27 V corresponds to the change from S to soluble high-order LiPSs (Li2Sx, 4 ≤ x ≤ 8) and the cathodic peaks at 1.94 V is ascribed to the change from soluble high-order LiPSs to insoluble low-order LiPSs (Li2S2 or Li2S).34 And two anodic peaks can also be seen in the 1st anodic scan, which is associated with the phase change from Li2S to LiPSs, and then to S.16 The current intensity of these peaks becomes much stronger after the initial cycle. This phenomena may be caused by the activation process of battery. Fig. 3B displays the initial ten charges/discharge profiles of Li–S battery using SbNs/separator at a current density of 0.1 A g−1. The first discharge curve shows two high voltage plateaus (one at 2.35 V and the other at 2.0 V). The initial discharge and charge capacities of Li–S battery using SbNs/separator are 707.5 mA h g−1 and 681.9 mA h g−1, respectively, corresponding to an initial coulombic efficiency (ICE) of 96.3%. After the initial cycle, the capacity increases gradually and reaches a highest value of 997.7 mA h g−1 at 9th cycle. This phenomena further confirms an activation process is involved in the battery. During the initial several cycles, the active materials are not fully activated due to some reasons, such as the restricted contacting with Li+ or electrons. After the active materials are fully activated, the charge–discharge capacities reach highest values.20,45
The comparison of the charge–discharge capacities of Li–S batteries using SbNs/separator and commercial separator at a current density of 0.1 A g−1 is also shown in Fig. 3C. For Li–S battery using SbNs/separator, a reversible capacity of 660.8 mA h g−1 is maintained after 100 cycles. Besides, the CE of Li–S batteries using SbNs/separator always approaches 100% after the initial cycle, which indicates an effective role of SbNs that plays in alleviating the shuttle effect of LiPSs.34 In the case of Li–S battery using a pristine separator, only a reversible capacity of 154 mA h g−1 is delivered after 100 cycles. It should be noted that Sb material contributes little capacity during the charge–discharge process, which can even be ignored (Fig. S7A†). Besides, the chemical valences of the Sb after electrochemical cycling remains unchanged, indicating its chemical stability in Li–S batteries (Fig. S8†). Fig. 3D further compares the rate capabilities of Li–S batteries using SbNs/separator and commercial separator. For Li–S batteries using SbNs/separator, it can deliver a reversible capacity as high as 920, 743, 579, and 423 mA h g−1, respectively, when cycled at 0.1, 0.2, 0.5, and 1 A g−1. When the current density was recovered to 0.1 A g−1, the reversible capacity recovers to 878 mA h g−1, indicating excellent electrochemical stability of the electrode. While for Li–S battery using a commercial separator, it exhibits a much worse rate capability compared to Li–S batteries using SbNs/separator. Only a reversible capacity of 221 mA h g−1 is obtained when cycled at 1 A g−1. To reveal the advantages of SbNs/separator to that of graphene/separator and Sb/separator, the cycling performance of Li–S batteries using Sb/separator and graphene/separator are tested. Fig. S9† shows the nitrogen Brunauer–Emmett–Teller (BET) adsorption measurement of the graphene. The BET surface of the graphene is about 390 m2 g−1. For Li–S batteries using graphene/separator, the initial discharge and charge capacities are 863.8 mA h g−1 and 993.5 mA h g−1, respectively (Fig. S10†). After 100 cycles, a reversible capacity of 353 mA h g−1 is maintained. For Li–S batteries using Sb/separator, the initial discharge and charge capacities are 760.3 mA h g−1 and 737.4 mA h g−1, respectively (Fig. S11†). After the initial cycles, the capacity increases gradually and reaches the highest value of 958.6 mA h g−1 at the 5th cycle. A reversible capacity of 320 mA h g−1 is maintained after 100 cycles. Obviously, the cycling performance of Li–S batteries using graphene/separator and Sb/separator are improved compared with Li–S batteries using a pristine separator. However, the cycling performance of Li–S batteries using graphene/separator and Sb/separator are still much worse than Li–S batteries using SbNs/separator. This is due to the combined physical and chemical absorption of LiPSs between LiPSs and SbNs, which maximum inhibits the shuttle phenomena of LiPSs. The polarization voltages of Li–S batteries using SbNs/separator, graphene/separator, and pristine separator are shown in Fig. S12.† It can be seen that the polarization voltage of Li–S batteries using SbNs/separator (ΔE = 0.159 V) is much lower than Li–S batteries using commercial separator (0.236 V) and graphene/separator (0.203 V), indicating SbNs/separator acts a positive catalyst role in facilitating the conversion of LiPSs.46,47
Electrochemical impedance spectrum of symmetric batteries with Li foil and commercial separator (or SbNs/separator) were tested (Fig. S13†). The Rf of symmetric battery with Li foil and SbNs/separator is a little larger than that of symmetric battery with Li foil and commercial separator, indicating the electrochemical impedance value of SbNs/separator is a little larger than that of commercial separator. Fig. S14† shows typical Nyquist plots of Li–S batteries using SbNs/separator (or commercial separator, discharged to 1.8 V after 10 cycles at a current density of 0.1 A g−1). Obviously, the charge transfer impedance of Li–S batteries using SbNs/separator is much smaller than that of Li–S batteries using a commercial separator. This is due to the good conductivity of metallic SbNs that facilitates the electron transfer to the adsorbed LiPSs and the catalyst role of SbNs in facilitating the conversion of LiPSs that avoids the accumulation of nonconductive Li2S.48–50 To confirm the positive effect of SbNs in adsorbing LiPSs, graphene and SbNs with the same total surface area were immersed in DOL/DME (1:
1, v/v) solution containing 0.005 mol L−1 Li2S6 as absorbents for one night. We can see that the SbNs exhibits much stronger polysulfide adsorption compared with that of graphene. The color of Li2S6 changed a lot in the solution using SbNs as absorbent (Fig. 4A). However, the color of Li2S6 has almost no change in the solution using graphene as absorbent, which demonstrates weak polysulfide adsorption of graphene. To further provide evidence of the chemical adsorption between LiPSs and SbNs, the XPS of SbNs that immersed in DOL/DME (1
:
1, v/v) solution containing 0.005 mol L−1 Li2S6 for one night was examined (Fig. 4B). As known, the pristine Li2S6 exhibits two pairs of typical peaks located at 161.3 and 163.8 eV, which ascribe to the terminal (ST−1) and bridging (SB0) sulfur, respectively. However, the peak of ST−1 shift to a high BE range in SbNs–Li2S6 composite, indicating a reduction in electron cloud density of sulfur atoms due to the chemical adsorption by SbNs.51 Besides, the peaks at 169.2 eV and 170.4 eV are assigned to sulfate and thiosulfate, respectively, which also indicates the chemical interactions between SbNs and Li2S6.51 The chemical adsorption of Li2S6 by SbNs is further supported by the Li 1s spectra of SbNs–Li2S6 composite (Fig. S15†). It has been revealed that the pristine Li2S6 displays a typical peak at 55.3 eV, corresponding to the Li–S bond. However, the Li–S bond shift to a lower bond of 54.9 eV. It suggests that a “lithium-bond” like configuration forms bridge the SbNs absorber and LiPSs.51
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Fig. 4 (A) Digital image of the Li2S6 (0.005 mol L−1) in DOL/DME solution: (a) control; adsorption by (b) graphene and (c) SbNs. (B) S 2p high-resolution XPS spectra of SbNs–Li2S6 composite. |
Based on the above discussion, the improved electrochemical performance of Li–S batteries using SbNs/separator is due to the following reasons: firstly, the combined physical and chemical absorption of LiPSs between LiPSs and SbNs efficiently inhibits the shuttle phenomena of LiPSs, which benefit the cycle stability of Li–S batteries. Secondly, the good electronic conductivity of SbNs facilitates the transfer of electrons to active material, which improves the rate performance of Li–S batteries. Besides, the catalytic effect from SbNs facilitates the fast conversion kinetics of intermediate LiPSs, which further suppresses the shuttle effect of LiPSs.
Footnotes |
† Electronic supplementary information (ESI) available. See DOI: 10.1039/d0ra10100a |
‡ Zeng L. and Zhu J. contributed equally to this work. |
This journal is © The Royal Society of Chemistry 2021 |