Jidan
Liu
*a,
Jinyuan
Jiang
a,
Zhenke
Yang
a,
Qiaohai
Zeng
a,
Jieying
Zheng
a,
Siying
Zhang
a,
Liyao
Zheng
a,
Shang-Shi
Zhang
b and
Zhao-Qing
Liu
*a
aSchool of Chemistry and Chemical Engineering/Institute of Clean Energy and Materials/Guangzhou Key Laboratory for Clean Energy and Materials, Guangzhou University, Guangzhou, P. R. China. E-mail: jdliu@gzhu.edu.cn; lzqgzu@gzhu.edu.cn
bCenter for Drug Research and Development, Guangdong Pharmaceutical University, Guangzhou, P. R. China
First published on 1st February 2021
Correction for ‘Rhodium(III)-catalyzed oxidative alkylation of N-aryl-7-azaindoles with cyclopropanols’ by Jidan Liu et al., Org. Biomol. Chem., 2021, DOI: 10.1039/d0ob02323j.
Entry | Rh catalyst | Additive | Oxidant | Yieldb (%) |
---|---|---|---|---|
a Reaction conditions: 1a (0.2 mmol), 2a (0.3 mmol), Rh catalyst (4 mol%), additive (20 mol%) and oxidant (2 equiv.) in MeOH (1 mL) in a sealed tube at 50 °C under N2 for 4 h. b Isolated yield of 3a based on 1a. c At 30 °C. d At 70 °C. e Cu(OAc)2·H2O (1.8 equiv.) was used. f Cu(OAc)2·H2O (2.1 equiv.) was used. g Cu(OAc)2·H2O (0.2 equiv.) was used. | ||||
1 | [Cp*RhCl2]2 | CsOAc | Cu(OAc)2 | 82 |
2 | [Cp*RhCl2]2 | CsOAc | PhI(OAc)2 | 9 |
3 | [Cp*RhCl2]2 | CsOAc | O2 | Trace |
4 | [Cp*RhCl2]2 | CsOAc | Ag2CO3 | 54 |
5 | [Cp*RhCl2]2 | CsOAc | AgOAc | 62 |
6 | [Cp*RhCl2]2 | CsOAc | Ag2O | 48 |
7 | [Cp*RhCl2]2 | CsOAc | Cu(OAc)2·H2O | 86 |
8 | [Cp*RhCl2]2 | KOAc | Cu(OAc)2·H2O | 83 |
9 | [Cp*RhCl2]2 | NaOAc | Cu(OAc)2·H2O | 75 |
10 | [Cp*RhCl2]2 | AgSbF6 | Cu(OAc)2·H2O | 43 |
11 | [Cp*RhCl2]2 | AgOAc | Cu(OAc)2·H2O | 36 |
12 | Cp*Rh(OAc)2 | CsOAc | Cu(OAc)2·H2O | 80 |
13 | Rh(Ph3P)3Cl | CsOAc | Cu(OAc)2·H2O | 14 |
14 | Cp*Rh(CH3CN)3(SbF6)2 | Cu(OAc)2·H2O | 22 | |
15 | [Cp*RhCl2]2 | CsOAc | Cu(OAc)2·H2O | 65c |
16 | [Cp*RhCl2]2 | CsOAc | Cu(OAc)2·H2O | 83d |
17 | [Cp*RhCl2]2 | CsOAc | Cu(OAc)2·H2O | 77e |
18 | [Cp*RhCl2]2 | CsOAc | Cu(OAc)2·H2O | 85f |
19 | [Cp*RhCl2]2 | CsOAc | Cu(OAc)2·H2O/O2 | 18g |
20 | CsOAc | Cu(OAc)2·H2O | nr | |
21 | [Cp*RhCl2]2 | CsOAc | nr |
The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.
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