Yan-Yan
Dong‡
ab,
Dong-Dong
Ma‡
a,
Xin-Tao
Wu
a and
Qi-Long
Zhu
*a
aState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter (FJIRSM), Chinese Academy of Sciences (CAS), Fuzhou 350002, China. E-mail: qlzhu@fjirsm.ac.cn
bUniversity of Chinese Academy of Sciences, Beijing 100049, China
First published on 18th November 2019
Developing earth-abundant, highly active, and durable electrocatalysts for the oxygen evolution reaction (OER) is of crucial importance for renewable energy conversion processes. Herein, we fabricated novel flower-like NiFe-layered double hydroxide nanostructures with electron-withdrawing anion intercalation and surface sulfurization via a two-step hydrothermal treatment. Benefiting from the dual-modified electronic structure of the surface active sites of NiFe-LDHs, the as-obtained catalyst showed excellent electrocatalytic activity for the OER, only demanding a low overpotential of 259 mV to achieve 10 mA cm−2 in 1.0 M KOH.
Recently, layered double hydroxides (LDHs) have attracted much attention due to their high tunability with brucite-like layers and intercalated anions.20,21 Their large interlayer distance can afford remarkably large electrochemically accessible surface areas.22 Meanwhile, the abundant and uniformly distributed metal active sites could lead to high catalytic activity and selectivity.23 Among them, NiFe-LDHs have shown great potential for the OER due to the synergistic effect between Ni2+ and Fe3+.24,25 However, the relatively poor intrinsic catalytic activity of the reactive sites of NiFe-LDHs inhibits further enhancement of their OER performance.26 Fortunately, the electronic structures and surface active sites of NiFe-LDHs can be adjusted by modification, such as anion intercalation, sulfuring, phosphating, hetero metal doping, defect introduction, etc., thus greatly improving their intrinsic properties.27–30 For example, Luo et al.28 confirmed that the interactions between the intercalated phosphorous oxoanions (H2PO2−) and the edge-sharing MO6 (M = Ni, Fe) layers can modify the surface electronic structure of the Ni2+ sites and thus enhance the OER performance. Xiang et al.31 introduced a surface sulfurization treatment to fabricate NiCo-LDH@HOS as a highly efficient and durable electrocatalyst for the OER. Yang et al.32 reported that the third metal doped into NiFe-LDHs can be incorporated into the lattices of the hybrid, thus modifying the chemical environment and boosting the electrocatalytic performance.
A careful analysis of these reports shows that the reduced electronic densities of the active sites induced by various modifications generally should be responsible for the enhancement of the activities of the NiFe-LDH based catalysts. This could be due to the fact that the higher-valent electrophilic Ni/Fe sites promote the nucleophilic addition of hydroxyls and water molecules on the catalyst surface and improve the absorption of the reaction intermediate during the OER process.33 Therefore, the introduction of strong electron-withdrawing anions could be an effective way to further improve their activities. Inspired by this, we speculate that the integration of electron-withdrawing anion intercalation and surface sulfurization could generate a significant synergistic effect for an efficient OER.
To support this hypothesis, herein we designed and fabricated molybdenum, sulphur and phosphorus oxoanion co-intercalated NiFe-LDH nanoflowers with surface sulfurization (Mo0.5PS-NiFe-LDH) using a simple two-step hydrothermal procedure. By adjusting the ratio of the dopants, the best Mo0.5PS-NiFe-LDH exhibits a remarkable activity for the OER with a low overpotential of 259 mV at 10 mA cm−2 in 1.0 M KOH, and maintains good stability during long-term electrolysis. The boosted OER electrocatalytic performance of this catalyst could be correlated to the optimal electronic structures of the active sites modulated by anion intercalation and surface functionalization.
The MoxPS-NiFe-LDH samples were fabricated by a two-step hydrothermal method which is schematically illustrated in Fig. 1a (for details see the Experiment section in the ESI†). The phase structures of the as-prepared samples were analysed by powder X-ray diffraction (PXRD). As shown in Fig. S1a,† all the samples exhibit the characteristic peaks of the LDH phase, consistent with the standard PDF card (PDF#40-0125). Upon the intercalation of molybdate (Mo7O246−) ions, the peak at 11.4° (labelled as the B region in Fig. S1a†) decreases due to the higher atomic scattering factor for Mo in the LDHs.34 Besides this, a broad peak appears at about 6.5° (labelled as the A region in Fig. S1a†) upon molybdate intercalation, indicating the presence of enlarged layer spacing due to the large size of the intercalated molybdate.35 The presence of Mo7O246− was further confirmed by FT-IR spectroscopy (Fig. S2†).35,36 After further introducing sulphur and phosphorus oxoanions, as well as surface sulfurization, lots of impurity peaks appear in PS-NiFe-LDH (Fig. S1b†), illustrating that the structure of NiFe-LDH can be easily disrupted, leading to other phases.37 By contrast, the PXRD patterns of MoxPS-NiFe-LDH are almost the same as those of Mox-NiFe-LDH, indicating that intercalation with molybdate can improve the structural stability of NiFe-LDH. The larger layer spacing has proven to be instrumental in mass transfer and thus will improve the electrocatalytic performance for the OER.22 Besides, the PXRD patterns of the contrast samples with different composition ratios were also recorded, which show their similar structures to the LDH phase (Fig. S1c and d†).
The structure and morphology of Mo0.5PS-NiFe-LDH were examined by scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution TEM (HRTEM) and energy-dispersive X-ray (EDX) spectroscopy. Although both NiFe-LDH and Mo0.5-NiFe-LDH show a flower-like shape (Fig. 2a and b), the size of the nanoflowers became smaller and the layers became thinner after the intercalation of molybdate.38 After intercalating sulfur and phosphorus oxoanions, the morphologies of both PS-NiFe-LDH and Mo0.5PS-NiFe-LDH were maintained well (Fig. 2c and d). The TEM images confirmed the nanoflower structures of Mo0.5PS-NiFe-LDH (Fig. 2e). The corresponding EDX elemental mappings demonstrate that the Ni, Fe, Mo, S, P and O elements are uniformly distributed in the nanostructure of Mo0.5PS-NiFe-LDH (Fig. 2i), suggesting the successful fabrication of the molybdenum, sulphur and phosphorus oxoanion co-intercalated NiFe-LDH materials. Notably, C mapping shows that no obvious C element was identified in the nanostructure, confirming that the CO32− anions, which are the main counter ions in pristine NiFe-LDH obtained under similar conditions,39 were almost replaced by molybdenum, sulfur and phosphorus oxoanions, which is in accordance with the decrease of the peak at 1383 cm−1, as shown in Fig. S2.†22,39 The atomic ratio of Ni, Fe, Mo, P and S elements was determined to be 4.8
:
1.9
:
1
:
3.7
:
1.5 by EDX (Fig. S3†), further confirming the successful doping of Mo, P and S based oxoanions and the majority of the phosphorus oxoanions.
To reveal the elemental composition, chemical status and particularly the change of electronic structure upon functionalization, X-ray photoelectron spectroscopic (XPS) analyses were conducted for the catalysts (Fig. 3). The deconvoluted spectra of Ni 2p, as shown in Fig. 3b, show two spin–orbit doublets, which are the characteristic peaks of Ni2+ and Ni3+, and satellites. The observed two main peaks for Mo0.5PS-NiFe-LDH at binding energy (BE) values of 856.07 and 873.45 eV with a spin–orbit splitting of 17.38 eV are ascribed to Ni 2p3/2 and Ni 2p1/2 with +2 oxidation state, respectively, while another pair of weak peaks at 859.87 and 875.42 eV suggests the existence of a small amount of Ni3+.40,41 The deconvoluted spectrum of Fe 2p for Mo0.5PS-NiFe-LDH (Fig. 3c) shows two peaks at BE values of 712.23 (Fe 2p3/2) and 725.49 eV (Fe 2p1/2), which signifies that iron exists in the Fe3+ state.34,42 Compared to those of NiFe-LDH, the Ni 2p and Fe 2p peaks of both Mo0.5-NiFe-LDH and Mo0.5PS-NiFe-LDH are shifted to the more positive energies, manifesting the strong interactions between the intercalated Mo, P and S based oxoanions and the Ni and Fe sites, which reduces the surface electron densities of the active sites.43,44 The Mo 3d spectrum of Mo0.5PS-NiFe-LDH splits into two main peaks of 2p5/2 and 2p3/2 at 232.24 and 235.29 eV, which are attributed to Mo6+ (Fig. 3d).45,46 After further intercalating the sulfur and phosphorus oxoanions, an obvious positive-shift of Mo6+ can be observed due to electron loss, indicating stronger electron-withdrawing properties of the sulfur and/or phosphorus oxoanions.47 In the S 2p spectrum of Mo0.5PS-NiFe-LDH (Fig. 3e), the BE values at 162.42 and 164.12 eV ascribed to S 2p3/2 and S 2p1/2 correspond to the metal–sulfide (M–S) bonding,48,49 while the peaks at 168.10 and 169.20 eV are assigned to the sulphur oxoanions.50,51 The results illustrate that some of the S atoms were bonded with metals by replacing the O atoms in the edge-sharing MO6 units to form surface metal sulfides and the rest of the S atoms were oxidized and then replaced the interlaminar CO32− ions, which is consistent with the EDX mapping results. As presented in Fig. 3f, the only peak of P 2p at 132.9 eV is associated with the oxidized P species.52,53 The XPS results reveal the successful intercalation of molybdenum, sulfur and phosphorus oxoanions and surface sulfurization in Mo0.5PS-NiFe-LDH, which generate a strong synergistic effect and modulate the chemical environments and electronic structures of the active Ni and Fe sites for electrocatalysis.
The electrocatalytic OER performances of MoxPS-NiFe-LDH (the molar ratio of Ni:
Fe of the samples was 3
:
1 except for special instructions) were examined in 1.0 M KOH using a typical three-electrode system (for details see the ESI†, Electrochemical measurements). For comparison, NiFe-LDH, PS-NiFe-LDH, Mo0.5-NiFe-LDH and the commercial benchmark RuO2 catalyst were measured under the same conditions. According to the linear sweep voltammetry (LSV) polarization curves shown in Fig. 4a, the OER activities of the catalysts with different functionalizations were apparently improved as indicated by the considerable negative-shift of the polarization curves (Fig. 4a, Mo0.5PS-NiFe-LDH vs. PS-NiFe-LDH, Mo0.5-NiFe-LDH vs. NiFe-LDH), which can be ascribed to the larger layer spacing, electron interactions and synergistic effect between the intercalated oxoanions and the electrochemically active sites of the LDH.54,55 Besides, surface sulfurization may also enhance the OER properties due to the modification of the electronic structure (Fig. 4a).33,56 Meanwhile, the Ni2+/Ni3+ oxidative peaks of Mo0.5PS-NiFe-LDH at ca. 1.4 V (vs. RHE) were significantly decreased, which may originate from the reduction of ammonium hypophosphite and further implies the modification of the electronic structure of the active sites upon the intercalation of the phosphorus oxoanion.28,57 In comparison, the Mo0.5PS-NiFe-LDH catalyst delivered higher current densities and more negative OER onset potentials than NiFe-LDH, PS-NiFe-LDH, Mo0.5-NiFe-LDH and RuO2. Particularly, Mo0.5PS-NiFe-LDH showed the lowest overpotential of only 259 mV to achieve a current density of 10 mA cm−2 (Fig. 4b). To further investigate the influences of the molar quantity of the Mo element, reaction time, Ni/Fe ratio and functionalization on the catalytic activity, a series of other comparative samples were synthesized and tested (Fig. S4†). It was obvious that Mo0.5PS-NiFe-LDH showed a much better catalytic performance than those of the contrast samples.
The catalytic kinetics of the catalysts were evaluated using the Tafel slope and electrochemical impedance spectroscopy (EIS). As shown in Fig. 4c, Mo0.5PS-NiFe-LDH presents the smallest Tafel value (62 mV dec−1), compared to RuO2 (121 mV dec−1), NiFe-LDH (85 mV dec−1), PS-NiFe-LDH (82 mV dec−1), and Mo0.5-NiFe-LDH (78 mV dec−1), indicating the fastest OER kinetics. The semicircles shown in Fig. 4d are Nyquist plots obtained at the overpotential of 274 mV. The semicircles in the EIS curves correspond to the charge transfer resistance (Rct), which is related to the OER kinetics occurring at the electrode/electrolyte interface. Apparently, Mo0.5PS-NiFe-LDH shows the smallest Rct value, illustrating that it has relatively low charge transfer resistance and superior charge transport kinetics, owing to its nanoflower morphology and structural funactionalization.58,59 The results prove that Mo0.5PS-NiFe-LDH showed better kinetics than the other catalysts.
To reveal the high electrochemical performance of Mo0.5PS-NiFe-LDH for the OER, the electrochemically active surface area (ECSA) was estimated from the double-layer capacitance (Cdl) by carrying out CV tests in the non-faradaic region (Fig. S5†). As shown in Fig. 4e, the Cdl value of Mo0.5PS-NiFe-LDH was calculated to be 17.2 mF cm−2, which is apparently larger than those of NiFe-LDH (10.1 mF cm−2), PS-NiFe-LDH (10.7 mF cm−2), and Mo0.5-NiFe-LDH (14.3 mF cm−2). This result indicates that Mo0.5PS-NiFe-LDH is capable of providing more active sites to enhance the electrocatalytic OER activity.30,35,60
In addition to the improved catalytic activity, Mo0.5PS-NiFe-LDH showed high stability during the long-term OER reaction. As shown in Fig. S6,† three parallel Mo0.5PS-NiFe-LDH samples were tested and they showed good repeatability. After successive CV scanning for 1000 cycles, the overpotential increased only 12 mV at the current density of 10 mA cm−2. Meanwhile, chronoamperometry of Mo0.5PS-NiFe-LDH was further performed under electromagnetic stirring, and the curve shows that the catalytic current density was well maintained over 40000 s (Fig. 4f). These results demonstrate the excellent electrocatalytic stability of the Mo0.5PS-NiFe-LDH catalyst. For better understanding the catalytic activity and durability, the morphology and composition of Mo0.5PS-NiFe-LDH after the OER test were further characterized by PXRD, SEM and XPS. As shown in Fig. S7,† the characteristic diffraction peaks of the sample were maintained, illustrating that no new crystalline phase was formed during the test and the LDH structure remained unchanged. The XPS measurement for Mo0.5PS-NiFe-LDH after the stability test shows no obvious change in the high-resolution Ni 2p, Fe 2p, Mo 3d and P 2p spectra (Fig. S8†). However, the valence state of S was changed and the strength of M–S bonds was decreased, revealing that the S-based species could be reconstructed to form surface metal hydroxysulfides and thus influenced the surface electronic structure during the OER test. The SEM image showed that the sample presented a flower-like but thicker lamellar structure than that before the OER test (Fig. S9†), which may result from the surface reconstruction and the residual Nafion membrane covering the sample surface. The above results indicate that the surface electronic structure was further adjusted during the OER process to probably obtain abundant Ni2+/3+/Fe3+ sites and surface metal hydroxysulfides as the active species, thus leading to high catalytic performance.5,30,31,50,53,61–64
Footnotes |
† Electronic supplementary information (ESI) available. See DOI: 10.1039/c9qi01367a |
‡ Y.-Y. D. and D.-D. M. contributed equally. |
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