Xia
Wei
and
Xieraili
Maimaitiyiming
*
Key Laboratory of Energy Materials Chemistry, Ministry of Education, Key Laboratory of Advanced Functional Materials, Autonomous Region, Institute of Applied Chemistry, Key Laboratory of Oil and Gas Fine Chemicals, Educational Ministry of China, School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi, 830046 Xinjiang, P. R. China. E-mail: 380731363@qq.com
First published on 14th October 2019
The use of copolymers to extract and purify semiconducting SWCNTs (sc-SWCNTs) and metallic SWCNTs (m-SWCNTs) is widely employed. In this paper, the performances of two pyrimidine-alt-dioctylfluorene conjugated polymers in the enrichment of semiconducting SWCNTs are compared, and the subtle structural effects on them are discussed. It was found that both pyrimidine-polymers were more effective in wrapping the semiconducting SWCNTs than the metallic SWCNTs under the co-action of the pyrimidine and fluorene rings. Moreover, methyl groups on the pyrimidine ring of the polymer slightly contributed to the semiconducting purity, and the minor differences of sc-SWCNTs extraction between two pyrimidine-polymers are compared. Additionally, the average diameter of the selected SWCNTs is larger than that of the raw SWCNTs. The experimental results show the excellent selectivity for sc-SWCNT from both co-polymers: the index Φi values for determining the purity of sc-SWCNTs were increased from 0.408 for P2 to 0.465 for P1, of which the selected sc-SWCNT purity is up to 99.9%. The resulting purity and the inexpensive availability of pyrimidine co-polymers make them suitable to be considered for effective sc-SWCNT enrichment.
Semiconducting carbon nanotubes (sc-SWCNTs) are the ideal channel materials for building super-performance field-effect transistors, chemical sensors and micro-logic circuits for high-precision electronics due to their high carrier mobility, large current-to-switch ratio, and good stability.4–6 Therefore, obtaining high-purity sc-SWCNTs is of great significance for applications in nanoelectronic devices and other fields. The controllable achievement of high-quality sc-SWCNTs is consistently a focal research point these days. In the current research, high-purity sc-SWCNTs are often obtained by two methods, namely, the direct controllable preparation of high-quality sc-SWCNTs and the extraction of sc-WCNTs from commercial SWCNTs.7,8 Due to the complicated process and high cost of the former method, the latter was chosen to selectively enrich sc-SWCNTs using conjugated polymers on the basis of previous works.9–11 This method is not only easy to operate, but also controllable depending on the designable polymer.
Previous studies have shown that conjugated polymers, such as fluorene and fluorene derivatives, have good selectivity for large-diameter carbon nanotubes.12–14 In recent decades, Adronov et al. reported that a large number of scientific studies have been proposed to investigate the performance of fluorene derivatives for the separation and enrichment of sc-SWCNTs and m-SWCNTs.15–18
Due to its large electronic delocalization system, fluorene was found to combine with carbon nanotubes by π–π stacking.18–21 Researchers have been dedicated to studying a set of rules to further explain the mechanism of interaction between polymers and SWCNTs. Various kinds of conjugated polymers were synthesized, and different extraction behaviors were discussed with different monomers.22
Some studies on fluorene-alt-pyridine copolymer (synthesized by pulsed laser vaporization) have been reported to enrich large diameter sc-SWCNTs.23–26 In addition, the fluorene-alt-pyridine-3,5-diyl reported in the literature27,28 showed dispersibility, rather than selectivity, for SWCNTs in toluene solution. This can be attributed to the fact that the nitrogen atom of the nitrogen-containing aromatic heterocycle owns a pair of lone electrons, compared to the aromatic ring having p-electron π bond, and thus the affinity of the nitrogen-containing aromatic heterocycle to SWCNTs exhibits greater than that of fluorene to some extent. Therefore, it is meaningful to explore the pyrimidine ring with more than one N atom to selectively enrich sc-SWCNTs, in which relative wide energy gaps exist in comparison to m-SWCNTs.
In our work, fluorene-alt-pyrimidine-4,6-diyl conjugated polymers synthesized using a fluorene monomer and pyrimidine through the Suzuki coupling reaction were introduced, and their selectivity to plasma SWCNTs was investigated. The polymer/SWCNT dispersions were obtained by a simple ultrasonic dispersion and centrifugation. Then, the products were characterized by UV-visible-near-infrared (UV-vis-NIR), resonant Raman spectroscopy and photoluminescence spectroscopy (PL) and the results were discussed. Compared with previous studies, it was found that the polymer, in which the pyridine ring was replaced by the pyrimidine ring, exhibited a higher selectivity for sc-SWCNTs. Furthermore, in comparing the ability of the polymers for wrapping the SWCNTs, the presence of methyl groups on the 2-position of the pyrimidine ring of the polymer was found to selectively enrich sc-SWCNTs with high purity by more than 99.9%. By analysing the SWCNT enrichment with the two polymers presented in this work and comparing with previous works, a proposition is presented for a future molecular design to separate high-purity sc-SWCNTs.
The SWCNTs were separately extracted and enriched by the two polymers with different substituents at a ratio of 1.5:
1, and the results of the UV absorption spectra are compared in Fig. 1a. Compared to P2, a relatively deep gully appeared in the P1 (black) spectrum at 600–750 nm (assigned to the v1 → c1 transition of m-SWCNTs), which indicates the presence of a purer semiconducting SWCNT type. In addition, there were identical peak profiles within the range of 750–1200 nm. The absorption peaks of the SWCNT dispersions extracted by P1 were expressed more clearly than those of the P2-extracted SWCNTs (red). This indicated the thorough dispersion of raw SWCNTs by both P1 and P2, but a slightly poorer selectivity of P2, which can be mainly explained by the strong Van der waals force between the raw SWCNTs and P2 molecules in the P2-extracted system. In addition, this result was derived from the former's more facile v2 → c2 transition (S22) of sc-SWCNTs, preliminarily indicating the higher selectivity of P1 to sc-SWCNT. Compared to the literature,27 both pyrimidine-polymers in our work exhibited more appreciable selectivity than the pyridine-polymers. This may be due to the fact that compared to the pyridine ring, the increased number of N atoms on the pyrimidine ring induces the enhancement of the total number of free electrons, making it more inclined to select sc-instead of m-SWCNTs. For P1, its slightly higher selectivity for sc-SWCNTs can be explained by the overlap between one of the sp3 orbitals of the methyl group and the π-orbital on the pyrimidine unit in a phase-consistent direction.32,33 Due to the weak electron-donating ability of the methyl group, the electrons are uniformly delocalized throughout the pyrimidine ring, making the entire system more rich in electrons. Furthermore, the introduction of methyl groups for P1 increases the steric hindrance and thus, the conformation stability of the P1 molecules.13 The total electron density calculation mapped with the electrostatic potentials (ESP) and the total energy of the three polymers are shown in Fig. 1b. Both P1 and P2 exhibit lower energy values and are more stable than P3, thereby decreasing the dispersion and increasing the selectivity.
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Fig. 1 (a) The UV absorption spectra of P1- (black) and P2-based (red) SWCNT dispersions. (b) The total electron density calculation of P1, P2 and P3. |
In addition, the reported method for estimating the relative purity of sc-SWCNTs can be approximated to evaluate the purity of the P1-enriched sc-SWCNTs.13,20 The Φi value is defined as the ratio of the peak area to the background area in the range of S22 and M11 in the absorption spectrum, which can be used to evaluate the purity of sc-SWCNTs in the sample. A Φi value that is greater than 0.4 corresponds to an excess of 99.9% of the sc-SWCNTs in the sample.10,14 The Φi values of the P1 and P2-enriched sc-SWCNTs at a ratio of 1.5:
1 correspond to 0.243 and 0.156, respectively (depicted in Fig. S2†).
The same polymer/SWCNT composites were measured at three excitation wavelengths of 532 nm (Fig. S3†), 633 nm and 785 nm to obtain the Raman spectra. RBM is a vibrational mode in which all carbon atoms move along the radial direction, and is thereby closely related to the nanotube diameter.34–39 The Raman spectra were collected at the three excitation wavelengths for the P1/SWCNTs and P2/SWCNTs, both of which were combined in the same substrate ratio of 1.5:
1. It can be clearly seen from the Raman spectrum in Fig. 2 that both the P1 and P2 polymers have a tendency of enriching the sc-SWCNTs from the raw SWCNTs. Although the P1- and P2-extracted products at a ratio of 1.5
:
1 both exhibited a small and broad peak at the range of 135–175 cm−1 (corresponding to -SWCNT) at 785 nm wavelength excitation, a more distinctly sharp peak appeared at 190–240 cm−1, corresponding to the characteristic peaks of sc-SWCNTs, which further confirmed the selectivity of P1 and P2 for sc-SWCNTs.
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Fig. 2 The RBM range of the Raman spectra with laser excitation at 785 nm (a) and the G-band range at 633 nm laser excitation (b) corresponding to the P1-, P2-extracted and raw SWCNTs. |
As depicted in Fig. 2b, the G band belongs to the stretching motion of the atom pair in the carbon tube; both spectra exhibited a G+ peak at the 633 nm laser excitation wavelength. The G+ band at 1590.81 cm−1 (1589.72 cm−1 for P2/SWCNTs) and the G− band at 1571.83 cm−1 of P1/SWCNTs were all sharper and clearer than those of P2/SWCNTs. In addition, the G− band of P1/SWCNTs was less intense and at a lower frequency compared to P2/SWCNTs, which was characteristic of the sc-SWCNTs. This result can be explained by the fact that the G+ band originated from the carbon atom vibrations of the sc-SWCNTs along the nanotube axial length orientation (LO), and the less intense and sharper G− band originated from the carbon atom vibrations of the sc-SWCNTs along the nanotube tangential orientation (TO) axis.29,30
It can be said that two factors contributed to the ability of the two polymers to extract sc-SWCNTs: first, it is the π–π stacking of the carbon nanotubes and the fluorene ring that play a main role in the extraction. Second, the existence of the pyrimidine ring negatively charges the polymer, and thus electrostatic attraction exists between the polymer and sc-SWCNTs. In addition, the presence of the methyl group attached onto the pyrimidine ring of the polymer (P1) increases the electron cloud density of the entire conjugated system, making it slightly easier for the π–π stacking and electrostatic interaction with the sc-SWCNTs. Furthermore, the presence of the methyl group increases the dihedral angles of the pyrimidine and fluorene rings from 166.6° of P2 to 167.1° of P1 according to the calculation. This change possibly increases the ability of the entire molecular chain to effectively wrap around the larger sized sc-SWCNTs; thus, the π–π interaction between P1 and the sc-SWCNTs is enhanced. The stability is further confirmed by the comparison of the HOMO and LUMO energy level difference between P1 (ΔE = 0.15353) and P2 (ΔE = 0.15201).
The absorption spectra of the P1/SWCNTs dispersion at different substrate ratios of P1:
SWCNTs and the unsorted SWCNTs dispersed in SDBS solution are presented in Fig. 3a, and show the absence of the metallic part in the sorted section. The selectivity increases regularly with a decrease in the amount of P1. Fig. 3b shows the purity of the P1-selected SWCNTs displayed with a Φi value of 0.438 at a substrate ratio of 0.5
:
1. In addition, the UV-vis-NIR spectrum of the P2/SWCNT dispersion is presented in Fig. S1† at different substrate ratios. The P2/SWCNT dispersion exhibits increasing selectivity of sc-SWCNTs with decreasing substrate ratio, and the Φi value reaches up to 0.408 at a substrate ratio of 0.5
:
1. It was demonstrated that both the P1- and P2-containing pyrimidine-4,6-diyls exhibited higher selectivity than pyridine-2,5-diyl. Fig. S4† shows the normalized absorption curves of the three sets of parallel samples of P1-extracted SWCNTs at a ratio of 0.5
:
1 at 942 nm, thus confirming the repeatability of the P1 extraction. The absorption intensities (Φi value) corresponding to the 942 nm peak reach up to 0.055 (0.417), 0.149 (0.413), and 0.087 (0.465). Furthermore, the purity level was compared between the as-obtained SWCNTs by P1 at a ratio of 0.5
:
1 and the sc-SWCNTs with high purity (99.9%) from Nanointegris (Fig. S5†), and a higher purity was found to be obtained in our work. The P1/SWCNTs at a substrate ratio of 0.5
:
1 (Fig. 4) was selected for further discussion. The strong absorption in the range of 420–580 nm and 750–1200 nm are due to the v3 → c3 (S33) and v2 → c2 transitions (S22) of the sc-SWCNTs, and almost no v1 → c1 transition of the m-SWCNTs at 600–700 nm can be observed (the background is mainly due to the non-nanotube carbon impurities).20 This may be attributed to the fact that the aggregates of SWNCTs were fully dispersed in the solution containing polymer during ultrasonication.
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Fig. 4 Fluorescence emission intensity (left) and absorption spectra (right) of the sample films of polymer P1 and P1/SWCNTs compounds (0.5![]() ![]() |
The combination of SWCNTs with polymers weakened the π–π interaction between SWCNTs. This, in turn, led to the promoted integration of SWCNTs and polymers.15 The results obtained from the UV absorption spectra above can be further understood by the G-band analysis of resonance Raman spectroscopy. The Raman spectra of the P1/SWCNT (0.5:
1) film were also obtained with the 532 nm, 633 nm and 785 nm laser excitation wavelengths (Fig. 3b–d). The Raman spectra (Fig. 3c) of the P1/SWCNTs and unextracted raw plasma (dispersed in dichloromethane and evenly distributed on the silicon wafer by the drop-coating method) were obtained using laser excitation at 785 nm. In the RBM, the yellow part represents P1/SWCNTs showing the characteristic peak of the sc-SWCNTs. Comparatively, the characteristic absorption region of the m-SWCNTs presented in the green portion of the raw SWCNTs shows the strong discrimination ability of P1 to sc-SWCNTs.11–15 In the resonance Raman spectra excited by the 633 nm laser (Fig. 3d), a strong contrast was observed with the raw plasma SWCNTs of the G peak. The P1/SWCNTs at 1591.45 cm−1 of the G+ band was assigned to the LO axial vibrations of the C atoms on sc-SWCNTs. In raw plasma, the G− peaks of the m-SWCNTs were wider, while the G− peak of the sc-SWCNTs of P1/SWCNTs were sharper and less intense. The intensity ratios of the G/D bands (peaks at 1591.45 cm−1, 1309.23 cm−1, respectively) for P1/SWCNTs are ∼8.86, implying that the SWCNTs treated with polymer sonication not only had high purity, but retained their structure well. Moreover, it has been proven that the RBM mode under different laser excitation wavelengths has a characteristic property: the diameter of the corresponding SWCNTs increases in a certain chirality index range with decreasing ωRBM.40–43 From Fig. S3,† it can be seen that the enriched sc-SWCNTs (red) exhibited a redshift with respect to the raw SWCNTs (black) with a difference of 11 cm−1. The peak width was relatively narrow, resulting in a larger average diameter compared with the raw SWCNTs.
The fluorescence emission intensity (left) and absorption spectrum (right) of both thin films of the polymer P1 and P1/SWCNTs (0.5:
1) composite are shown in Fig. 4. The interaction of P1 with SWCNT enhanced the optical coupling between the ground state and the lowest excited state, passing through a significant blue shift with a fluorescence peak change from 473 nm of P1 (2.62 eV) to 435 nm of P1/SWCNTs (2.85 eV). The fluorescence of the composite was significantly weaker than that of the polymer itself under the illumination of the ultraviolet lamp, indicating that the presence of the SWCNTs caused significant photoquenching, which is consistent with the literature.44–46 The possible reason for this is that the energy difference existing between P1 and SWCNTs caused a photoinduced charge transfer at the interface between the two.47–51 Subtle changes exist in the absorption spectra of the P1 film and its solution, including a more blunt peak than that of the P1 solution, which is the result of its interaction with the thin surface.52,53
The PL measurement of SWCNTs dispersed in surfactants, and the electron absorption and emission transitions of more than 30 sc-SWCNTs have been revealed. However, because the metallic SWNTs have no band gap, fluorescence spectroscopy cannot specify the helical index of the metallic SWNTs. In addition, since large numbers of SWNT arrays, surface-grown SWNTs and nanotube bundles contain metallic SWNTs, the fluorescence of the semiconducting SWNTs is quenched, so fluorescence spectroscopy can only identify the spiral index of the single SWNT in suspensions and solutions. Therefore, the assignment (n, m) of the sc-SWCNT is generally identified using a fluorescence spectrum. PL maps were recorded for the P1/SWCNT dispersions (0.5:
1) depicted in Fig. S6.† The locations of various SWCNT fluorescence maxima were assigned according to previously published data.49,50 The intensities of sc-SWCNTs were observed, with most intense peak corresponding to the (10, 9), (12, 4) and (12, 5) chiralities. In addition, it is obvious that redshifts occur in the range of 1500–1600 nm upon excitation. This may be attributed to the π–π stacking with SWCNTs after being wrapped by P1, which affected the excitation of photons to SWCNTs.
Footnote |
† Electronic supplementary information (ESI) available. See DOI: 10.1039/c9ra06819h |
This journal is © The Royal Society of Chemistry 2019 |