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Correction: Substituent-controlled racemization of dissymmetric coordination capsules
Kentaro
Harada
,
Ryo
Sekiya
,
Takeshi
Maehara
and
Takeharu
Haino
*
Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1, Kagamiyama, Higashi-Hiroshima, Hiroshima, 739-8526, Japan. E-mail: haino@hiroshima-u.ac.jp
First published on 24th April 2019
Abstract
Correction for ‘Substituent-controlled racemization of dissymmetric coordination capsules’ by Kentaro Harada et al., Org. Biomol. Chem., 2019, DOI: 10.1039/c9ob00388f.
The authors regret that there were errors in Fig. 7 and the graphic abstract. The correct graphics are shown below.
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| Fig. 7 The effect of the substituent on racemization. (a) 1c and 1d have a large dihedral angle of the bipyridyl arms, facilitating the access of the solvent molecule to the Cu(I) center. This promotes helicity inversion. (b) 1a has dihedral angles of the bipyridyl arms below 90°, preventing the solvent molecule from accessing the Cu(I) center. (c) The top views of the energy minimized structures of 4c and 4d. | ||
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