Apiwat
Dankeaw
ab,
Fabrizio
Gualandris
a,
Rafael Hubert
Silva
a,
Roberto
Scipioni
c,
Kent Kammer
Hansen
a,
Bussarin
Ksapabutr
b,
Vincenzo
Esposito
a and
Debora
Marani
*ad
aDepartment of Energy Conversion and Storage, Technical University of Denmark, Frederiksborgvej 399, Roskilde 4000, Denmark
bDepartment of Materials Science and Engineering, Faculty of Engineering and Industrial Technology, Silpakorn University, Sanamchandra Palace Campus, Nakhon Pathom, 73000, Thailand
cDepartment of Material Science and Engineering, Northwestern University, 2220 Campus Drive, Evanston, IL 60208, USA
dCentro de Engenharia, Modelagem e Ciências Sociais Aplicadas, Universidade Federal do ABC, Av. dos Estados 5001, Santo André, SP 09210-580, Brazil. E-mail: debora.marani@ufabc.edu.br; Fax: +45 4677 5688; Tel: +45 5171 9860
First published on 6th November 2018
Highly porous Ce–W–TiO2 free-standing nanofibrous membranes (FSM) are fabricated via electrospinning techniques to serve as NOx-SCR catalysts. The precursor of the ceramic nanofibers (sol–gel solution) is co-electrospun with poly(vinyl alcohol) (PVA) water solution. PVA integration into FSM has been proven to avoid excessive bending of the nanofibers and to prevent mechanical failure of the final ceramic nanofibrous structure. This is demonstrated to be associated with higher thermal stability of PVA compared with that of other organic additives. 3D tomography reconstruction indicates a resulting ceramic membrane with remarkable open and interconnected porosity of ca. 96%. Catalytic characterization, performed at the best working conditions (in absence of H2O and SO2), indicates that amorphous FSM is the best performing catalytic membrane. Superior catalytic performances of the developed FSM over those of other nanofibers and nanoparticle catalysts are proven because of superior surface, morphological, and structural features. Long-term stability (120 h) and reproducibility (over 5 cycles) of FSM are also demonstrated.
Environmental significanceNitrogen oxides (NOx) are recognized as major air pollutants responsible for serious damage to the environment and human health. The most efficient and cost-effective technology available to convert NOx into harmless products (nitrogen and water) is the selective catalytic reduction (SCR) method. Nanometric metal oxides electrospun as membranes hold great potential for their use as enhanced catalysts due to their merits such as high surface-to-volume ratios, wide-open and interconnected porous networks, and high porosity. However, the preparation of free-standing electrospun ceramic membranes is critical because of their mechanical integrity. Herein, by integrating a co-electrospun polymeric component, we demonstrate highly porous WO3–CeO2/TiO2 nanofibrous free-standing membranes, which exhibit superior de-NOx catalytic performances compared with nanofibers at the same composition. |
Besides the colloidal approach, in the recent years, electrospinning has emerged as a simple, inexpensive and versatile method for shaping materials into non-woven membranes composed of continuous nanofibers.15–20 The resulting nanofibrous membranes possess significantly high porosity (e.g., 80–90% (ref. 21)) that is associated with an arrangement of the nanofibers into a wide-open and well-interconnected porous network.21–25 As a class of one-dimensional (1D) nanomaterials with cross-sectional diameters ranging from tens to hundreds of nanometres, nanofibers further offer extremely high surface area-to-volume ratios. All these morphological features have been demonstrated to impart outstanding performances to the resulting nanofibrous ceramic membranes, especially in pressure-driven applications, such as for instance filters for the abatement of air pollutants. This is because the dimensions of the nanofibers match both the dimensions of particles to be captured and those of the molecular air flow parameters (e.g., λ, gas mean free path, for air at standard conditions is 68 nm).24,26 In addition, the electrospinning approach offers the advantage of easy control over the chemical compositions, allowing the preparation of a vast number of materials by simply adjusting the chemistry of the starting spinning solution.27
Despite many advantages, the preparation of free-standing thick ceramic electrospun membranes still remains critical because of the mechanical fragility of the nanofibers when flexed above their critical strain limits. Typically, titania nanofibers from sol–gel chemistry exhibit significant flexibility with decreased tensile strength and increased Young's modulus upon increasing calcination temperatures.28 However, the transition from the as-spun material, containing both organic and inorganic precursors, to the final polycrystalline metal oxide is accompanied by shrinkage of the materials, which can lead to strains easily above 50% of the initial dimensions.28 This might cause excessive bending of the single nanofibers, thus leading to fracture of the membrane into small fragments. A number of investigations have been conducted to prepare ceramic free-standing electrospun media.3,4,16,27 For instance, Wang et al. successfully prepared self-standing γ-alumina fibrous membranes by careful optimization of the spinning parameters and of the calcination conditions.4 Furthermore, Shahreen et al. proposed combining the fragile catalytic nanofibers with more mechanically stable micron fibres of alumina into fibrous catalytic media for the removal of NO and CO. The active nanofibers and the supporting microfibers were separately electrospun, calcined, and then mixed to form a water-based slurry that was finally dried under vacuum into a mold to form a cylindrical filter.24
Despite the promising performances obtained, the mentioned processing methods still suffer from limitations, the major one being the multi-step approach. A simple manufacturing method is highly desirable to reduce the production costs and time.
Herein, we address the issue by proposing a single-step approach based on the integration of an additional co-electrospun polymeric component into the nanofibrous structure, which can sustain catalytic nanofibers during the removal of the organics. Structural support is achieved by introducing a polymer with higher thermal stability compared to that of organic additives used in the electrospinning process. As a supporting polymer, we propose poly(vinyl alcohol) (PVA) that is co-electrospun together with precursor solutions of Ce–W–TiO2 into nanofibrous xerogel membranes. Upon calcination, highly porous free-standing electrospun membranes (FSMs) are produced, which serve as catalytic media for the abatement of NOxvia selective catalytic reduction (SCR). The composition of these ceramic nanofibers is fixed based on our recently reported results on the de-NOx efficiency of ceria-based catalysts.22 To the best of our knowledge, this is the first report on the preparation of highly porous free-standing electrospun ceramic membranes using a supporting co-electrospun polymeric component to control the structural stability of ceramic nanofibers.
The 3D structure of the membrane was evaluated by FIB/SEM (Zeiss 1540 XB Crossbeam Scanning Electron Microscope, Carl Zeiss Microscopy GmbH, Germany) using a lateral E–T (Everhart–Thornley) detector and an In-lens detector. A gallium FIB slicing probe of 1 nA was used and the thickness of each slice was estimated to be 13 nm. Serial sectioning imaging was performed at 1 kV with a pixel size of 24 × 24 nm2, yielding a voxel size in the 3D-data set of 13 × 24 × 24 nm3. The nanofibrous membrane was prepared for FIB/SEM microscopy by vacuum infiltration with epoxy resin (from Struers) to enable high-quality grinding and polishing of the sample. Segmentation of the 3D FIB/SEM image data was performed with the ImageJ program (NIH). The uneven illumination observed in the 3D dataset does not allow setting of a single threshold for the entire micrographs. Thus, the Sauvola algorithm29,30 was used to perform local thresholds for the data. This algorithm divides the input image into square windows (n × n pixels) and sets thresholds for each window based on the mean and standard deviation of the pixel intensities. Visualization of the 3D reconstruction of the analyzed data was then performed with the Avizo program (FEI). Pore size distribution (PSD) was calculated according to the method described by Münch et al.:31 the segmented 3D volume is filled with spheres of a given radius. By reducing the radius incrementally, more volume will be filled. The PSD is then obtained by correlating the incrementally filled volumes with the corresponding radii. The fiber length distribution (FLD) was calculated based on the average path length method between two opposite vertices. However, from a thorough analysis of the 3D tomogram, some nodes are also observed. Here, two or more adjacent fibers cross each other, leading to unavoidable uncertainties in the FLD calculations.
Based on these results, nanofibrous FSMs are calcined at temperatures higher than 500 °C to ensure the removal of any residuals. As indicated by the TGA profile, during the calcination process, green FSMs undergo considerable weight loss of around 75%, which clearly corresponds to an equally significant shrinkage of their volume. The latter can be empirically evaluated by measuring the membrane dimensions before and after calcination. Fig. 2a–d show the variation in lateral dimensions and thickness post-calcination at 500 °C. The ability of PVA co-electrospinning approach to provide the required structural stability is verified on a relatively large membrane, which represents the worst instance of internal mechanical stresses. A thermal conversion from green to pure ceramic nanofibrous FSM is indeed accompanied by contraction in volume of around 78%. It is worth noticing that despite significant shrinkage, the nanofibrous membrane retains its shape and above all its structural integrity. Moreover, a long range (hundreds of microns) elemental analysis (EDX, inset Fig. 2c) of the calcined nanofibers indicates a percentage molar ratio for Ti/Ce/W (1.0000/0.1822/0.0723), which is consistent with the molar ratio in the initial precursor solution, suggesting adequate dispersion of the cations both in the initial spinning solution and in the electrospun membranes.
Next, the effect of different calcination temperatures (all higher than 500 °C) on crystallinity is investigated. Fig. 3 shows the diffraction patterns for the ceramic nanofibers calcined at increasing temperatures. No peaks associated with crystallographic phases are observed for materials calcined at temperatures lower than 538 °C. For the sample calcined at this temperature, initial formation of the anatase phase of titanium oxide can be observed. A peak corresponding to the diffraction plane (101) is identified. In contrast, at higher temperatures (e.g., 550 °C), the occurrence of anatase titanium oxide (diffraction plane (101)) and fluorite cerium oxide (diffraction plane (111)) phases is detected. An effect of cerium dopant in inhibiting the formation of anatase phase is observed, which is supported by literature.21–23,35 This effect is likely due to large dimensional cation mismatch (Ce4+ (0.87 Å) vs. Ti4+ (0.60 Å) in 6-fold coordination) that, at lower temperatures (<550 °C), causes reduced elemental diffusion of the cations. By contrast, at temperatures higher than 550 °C, elemental diffusion is efficiently activated and the Ce-saturated TiO2 anatase phase crystallizes.22
Fig. 3 XRD patterns of Ce–W–TiO2 FSM calcined at different temperatures. The fluorite phase of cerium oxide is indicated with a star. |
Based on XRD patterns, further characterizations are only conducted on three selected samples: FSM@500, FSM@538, FSM@575; the three samples are selected as representatives of an amorphous state, an initial stage of phase formation, and a crystallographic phase, respectively.
The effect of calcination temperature on morphology is investigated by SEM and TEM (Fig. 4a–f) for the three selected samples. The micrographs refer to membranes previously cut into discs with diameter of around 15 mm after calcination (insets in Fig. 4b, d, and f). SEM images (Fig. 4a, c, and e) indicate defect-free nano-textured porous structures composed of nanofibers with high aspect ratios and narrow diameter distribution. Open and interconnected porosity is also observed and associated with a large porosity volume. A slight contraction of the diameter of nanofibers upon increasing the calcination temperature is observed and explained as an effect of the temperature (Table 1). Fig. 4b, d, and f show the corresponding TEM micrographs for the above discussed samples. In agreement with the XRD patterns, amorphous characteristics, corresponding to a smooth surface, are observed for the nanofibrous membranes formed when calcined at 500 °C (Fig. 4b). In the corresponding diffraction pattern obtained using a selected-area-electron diffraction (SAED) technique (inset in Fig. 4b), no signals for an ordered disposition of atoms within a crystallographic unit cell are observed. Instead, the initial formation of crystallites on the surface of nanofibers can be inferred for the membrane calcined at 538 °C (Fig. 4d). The incipient formation of a crystallographic phase is also supported by the corresponding SAED pattern (inset in Fig. 4d), where an early signal of the crystallographic phase can be identified. Eventually, characteristically rough surfaces and densely packed polycrystalline morphology are observed for the nanofibrous membranes calcined at 575 °C (Fig. 4f), which is confirmed by the corresponding SAED (inset in Fig. 4f).
Sample | Crystallographic phase | Average nanofiber diameter (nm) | Specific surface area (m2 g−1) | Pore volume (cm3 g−1) | Pore diameter (nm) |
---|---|---|---|---|---|
CeWTiO2@500 | Amorphous | 229 ± 42 | 59.89 | 0.08 | 3.5 |
CeWTiO2@538 | Anatase/fluorite | 219 ± 53 | 43.48 | 0.13 | 7.3 |
CeWTiO2@575 | Anatase/fluorite | 212 ± 59 | 38.88 | 0.13 | 9.1 |
The surface properties of the nanofibers, which are of critical relevance for understanding the catalytic performances, are also investigated. Fig. 5a shows the N2 adsorption–desorption curves, whereas pore volume, pore diameter, and specific surface area (SSA) data are summarized in Table 1. Adsorption curves for the three membranes follow a typical V type profile of mesoporous materials (pore diameter: 2–50 nm) with an H2 hysteresis loop. Interestingly, while the surface pore volume increases from the sample calcined at 500 °C to the sample calcined at 538 °C, it remains constant when the temperature is increased to 575 °C (Fig. 5b and Table 1). Continuous increment of the pore diameter values with temperature is instead observed (Fig. 5b and Table 1), which corresponds to decrease in the specific surface area (Table 1). The trends for surface parameters are observed due to temperature, which is expected to induce the growth of TiO2 crystallites.36
Next, the structural characteristics of the calcined FSM are investigated with the aim of achieving an insight into the porosity. Details on the porous membrane structure can be obtained via FIB/SEM analysis. Fig. 6a shows the SEM image of the membrane calcined at 500 °C after FIB slicing, which is recorded at high magnification with the In-lens detector at 1 kV. Inside the hole, dug with a gallium probe, two phases are observed: the white textural structure, which corresponds to TiO2 nanofibers, and the black bulk, which is the epoxy resin used to infiltrate the pores. 3D tomography reconstruction of sub-volume of the fiber-based membranes (7 × 15 × 8 μm3) is shown in Fig. 6b. The TiO2 fibers are represented in white, whereas the pores are shown as transparent. High porosity of the developed membrane is undeniably evident form the 3D reconstruction image. An analysis of the image provides an estimated value of around 96%; this is an extremely high value, and it is larger than the value of ca. 80% (ref. 21) reported in literature for a nanofibrous catalyst and that obtained by analyzing SEM micrographs (via estimation of the mean intercept length).37 The high porosity obtained for the nanofibrous FSM is likely due to PVA, which not only prevents excessive bending of the single nanofibers, but also limits shrinkage of the porous membrane during the thermal removal of alkoxides and PMMA. Further relevant details on both the porous network structure and nanofibers are shown in Fig. 7a and b, respectively. Fig. 7a indicates average pore diameter of around 650 nm, whereas Fig. 7b indicates average fiber length of around 12.3 μm. It is worth mentioning that the latter value is influenced by the dimension of the volume analyzed, and its value is expected to be higher when the entire volume of the membrane is considered.
Fig. 6 (a) SEM micrograph of FSM calcined at 500 °C after FIB slicing, and (b) the corresponding 3D FIB tomography reconstruction of a sub-volume (7 × 15 × 8 μm3). |
Fig. 7 (a) The pore size distribution and (b) the fiber length distribution corresponding to FSM calcined at 500 °C. |
The catalytic activity of the developed membranes is then explored, and the obtained information is used to better understand the performances. The aim of the study is characterization of the intrinsic catalytic activity of highly porous FSM. Accordingly, experiments are conducted in dry conditions and in the absence of SO2. FSMs in the shape of discs with diameter of 15 mm (after calcination) and thickness of approximately 100 μm are tested. Each catalytic disc corresponds to an extremely low weight of material (CeWTiO2) of around 8 mg.
Fig. 8a shows NOx conversion as a function of reaction temperature for the three membranes FSM@500, FSM@538, and FSM@575. Three regions in the catalytic activity of the materials can be identified: low, intermediate, and high temperatures. In the first region, the NOx conversion values are low and almost constant, whereas a steady increase is observed in the intermediate range of temperatures until a plateau, corresponding to the maximum NOx conversion at approximately 300 °C. This represents the regime region, where the reaction is only controlled by the transport of reagents. Interestingly, for all three investigated catalysts, NOx conversion declines at temperature as high as 500 °C, which is likely due to the increased rate of ammonia oxidation at these temperatures.38 In the intermediate temperature region, differences in NOx conversion trends for the three samples are observed; amorphous FSM (FSM@500) is the best performing material, and this is characterized by conversion values of around 60% and 90% at 200 °C and 250 °C, respectively. Details on the reaction mechanism are obtained by exploring kinetics of the process.39 Estimation of the activation energy (Ea) and of the number of active sites associated with the pre-exponential factor (A) can be obtained by the Arrhenius fitting of the experimental data. Fig. 8b shows Arrhenius plots for the three catalytic membranes, whereas the corresponding fitting parameters together with Ta are reported in Table 2. In the region at the lowest temperatures, Arrhenius analysis is not conducted because of the insufficient number of experimental data (only two). At the intermediate range, the plot indicates a reaction dependent on temperatures, whereas at the high-temperature region, no dependence is observed with activation energy values (Ea) close to zero. The transition from the intermediate to the regime region shifts to higher values with increased calcination temperature of the catalytic membranes (inset in Fig. 8b). The observed trend follows the order FSM@500 < FSM@538 < FSM@575. The amorphous catalyst has the lowest activation temperature (259 °C) and thereby, it is characterized by the widest regime region. Interestingly, regardless of the calcination temperature and the crystallographic phase, similar Ea values are observed, suggesting similar reaction mechanisms for the three catalytic FSMs. In contrast, a significant difference in the pre-exponential factors (A) is obtained. Specifically, similar numbers of active sites (within experimental errors) are observed for FSM@500 and FSM@538, whereas the lowest number of active sites is associated with FSM@575, which is likely due to the highest calcination temperature. Overall, superior catalytic performance is obtained for FSM@500, which is possibly due to the amorphous phase and correspondingly larger specific surface area (Table 1). Indeed, the amorphous phase is generally regarded as promising for a substrate for catalysis as it is considered chemically homogeneous with respect to the related surface properties.22,40,41
Fig. 8 (a) SCR activity of Ce–W–TiO2−δ FSM calcined at 500 °C, 538 °C, and 575 °C and (b) the corresponding Arrhenius plots. |
Sample | Activation energy, Ea (kJ mol−1) | Pre-exponential factor, A | Activation temperature, Ta (°C) |
---|---|---|---|
CeWTiO2@500 | 40.10 ± 3.60 | 6.16 × 106 ± 0.15 × 106 | 259 |
CeWTiO2@538 | 41.74 ± 2.15 | 7.34 × 106 ± 0.23 × 106 | 274 |
CeWTiO2@575 | 40.38 ± 2.28 | 2.87 × 106 ± 0.11 × 106 | 300 |
The catalytic performance of FSM@500 is further explored. In Fig. 9a, the NOx conversion values at different values of gas hourly space velocity (GHSV) are plotted as a function of temperature. As expected, high conversion (∼98%) is obtained at the lowest values of GHSV (163000 h−1 and 326000 h−1) within a relatively wide range of temperature (300–450 °C). Notably, at GHSV of 653000 h−1, the catalyst still retains an NOx conversion value of around 90%. Fig. 9b shows the comparison for NOx conversions by CeWTiO2 nanofibers and by the state-of-the-art V–W–TiO2 nanofibers and nanoparticles (as provided by Haldor Topsøe, Denmark). For clarity, the reference materials are hereafter indicated as CeWTiO2-NF, V–W–TiO2-NF, and V–W–TiO2-PWD HD. The nanofibrous FSM undoubtedly exhibits the highest conversion values in the entire range of investigated temperatures and at different GHSV experimental conditions. This can be ascribed to the extended and highly porous network, which is characteristic of nanofibrous FSM and enables a favourable fluid-dynamic regime through the membrane. In such a structure, any single nanofiber can be considered as a nanoreactor arranged with other nanofibers into a highly porous and lightweight SCR unit. In Table 3, a comparison between NOx conversions of nanofibrous FSM developed in the current study and literature data from both ceria-based mixed oxide nanofibers and nanoparticles22,42–44 is displayed. The comparison is only reported at temperatures lower than 300 °C (150 and 200 °C) before the catalysts reach the regime region. Superior catalytic behavior of nanofibrous FSMs is observed over both the nanofibers and nanoparticles. Indeed, conversion values of around 30% and 73% are obtained at 150 °C and 200 °C, respectively, for FSM at GHSV of 163000 h−1; at the same temperatures, the literature data indicate conversion values of around 15% and 40–60%, respectively, at any GHSV values (e.g., 25000, 200000, and 250000 h−1).22,42–44
Catalyst | [NH3][NO] (ppm) | GHSV (h−1) | NOx conv. (%) @150 °C | NOx conv. (%) @200 °C | Ref. |
---|---|---|---|---|---|
Ce1W1TiOx powder | 500 | 250000 | 10 | 50 | 38 |
Ce1W1TiOx powder | 500 | 25000 | 15 | 60 | 39 |
Ce3W1TiOx powder | 1000 | 200000 | <10 | 40 | 40 |
Ce2.6W1TiOx Nanofibers | 1000 | 200000 | 19 | 56 | 22 |
Ce2.6W1TiOx nanofibers | 1000 | 400000 | 16 | 51 | 22 |
Ce2.6W1TiOx nanofibrous membranes (FSM@538) | 1000 | 163000 | 30 | 73 | Current study |
Ce2.6W1TiOx nanofibrous membranes (FSM@538) | 1000 | 326000 | 24 | 64 | Current study |
Long-term stability of the FSM@500 sample is also investigated over time frames of 120 h, at 300 °C, and at 326000 h−1 (Fig. 10a). Remarkably, the material exhibits a stable and high de-NOx conversion value over the entire range of time frame investigated. No loss of activity is observed for the catalysts after a continuous long-term stability test (inset) compared to that for fresh materials. The stability of the material after 5 catalytic cycles is also verified (Fig. 10b). The reproducible conversion profiles observed further confirm the high stability of the developed FSM at working conditions. Notably, FSM@500 disc still retains its integrity after 5 SCR testing cycles (Fig. 10c).
The surface and morphological features of the nanofibers along with structural and porosity characteristics of the resulting FSM are definitely the main factors responsible for the exceptional catalytic performances. Indeed, these characteristics are expected to favor a fluid-dynamic regime that enables efficient exposure of the active sites to the reactant gases, thereby enabling high NOx conversion levels: values as high as 95% at GHSV of 326000 h−1 are observed over a wide range of temperatures. Moreover, high conversion values (ca. 90%) are maintained even at high gas speeds (653000 h−1). Notably, a comparison with nanofibers (NFs) of the same composition indicates superior performances for nanofibrous FSM. Besides, high long-term stability over multiple working cycles is also demonstrated.
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