Junais Habeeb
Mokkath
Department of Physics, Kuwait College of Science And Technology, Doha Area, 7th Ring Road, P.O. Box 27235, Kuwait. E-mail: j.mokath@kcst.edu.kw
First published on 30th November 2017
Using first-principles time-dependent density functional theory calculations, we investigate the shape-anisotropy effects on the optical response of a spherical aluminium nanoparticle subjected to a stretching process in different directions. Progressively increased stretching in one direction resulted in prolate spheroid (nanorice) geometries and produced a couple of well-distinguishable dominant peaks together with some satellite peaks in the UV-visible region of the electromagnetic spectrum. On the other hand, progressively increased stretching in two directions caused multiple peaks to appear in the UV-visible region of the electromagnetic spectrum. We believe that our findings can be beneficial for the emerging and potentially far-reaching field of aluminum plasmonics.
Optical responses in metal nanostructures can be accurately calculated using classical electromagnetic simulations based on Maxwell's equations.17,18 However, as the size is reduced below 10 nanometers, quantum mechanical effects emerge and classical simulations inevitably fail,19,20 and the quantum mechanical techniques such as time-dependent density-functional theory (TDDFT) are essential. In this Communication, we report the time-dependent density-functional theory study of anisotropy effects on the optical response of aluminium nanoparticles. To the best of our knowledge, it is the first time that the optical response of non-spherical aluminium nanoparticles has been studied by means of the TDDFT technique. The specific choice of aluminium for this work is justified as follows. Aluminium nanostructures have been drawing significant attention due to their enthralling optical response in the UV-visible region of the electromagnetic spectrum.21–25 Apart from this, the use of aluminium for modeling is not only computationally convenient because of the 3 valence electrons per atom needed in its description, but it has also been successful in reproducing many general phenomena of simple and noble metals in plasmonics. We consider spherical aluminium nanoparticles (807 atoms and 2421 electrons) subjected to a progressively increased stretching process leading to the formation of non-spherical nanoparticles. It is worth noting that the quantum mechanical treatment of the optical response is highly demanding for this size owing to the large number of electrons involved in the optical response. Our results reveal a complex evolution of the optical response as a function of the stretching process. We show that progressively increasing the stretching parameter in a spherical aluminium nanoparticle in just one direction leads to a nanorice-like geometry and the spectra exhibit focused and well-distinguishable peaks together with some satellite peaks. This result is consistent with the previous studies predicting that a nanorice geometry possesses a far greater spectrum tunability than a nanorod, along with much larger local field intensity enhancements.16 On the other hand, progressively increased stretching in two directions leads to complex structure modifications and multiple peaks to appear in the spectra.
Selected snapshots of the stretching process are shown in Fig. 1 and 2 for stretching in one and two directions, respectively. Following a ground-state density functional theory calculation using the BP-86 GGA xc-functional, the optical spectra are obtained by solving time-dependent Kohn–Sham equations using the well-known Casida's method26 as implemented in the Turbomole code.27,28 We use the triple-zeta plus polarization (TZP) basis set. The multipole-accelerated resolution of identity method is used for the Coulomb term, and quadrature grids of m3 quality are employed. The optical spectra are computed by solving the following eigenvalue equation,
ΩFI = ωI2FI | (1) |
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Fig. 1 TDDFT calculated optical spectra for stretching in one direction in which the stretching parameter progressively increased from 0 to 3. |
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Fig. 2 TDDFT calculated spectra for stretching in two directions in which the stretching parameter progressively increased from 0 to 3. |
We start our discussion by analyzing the optical response evolution found in the calculated spectra shown in Fig. 1 for stretching in one direction in which the stretching parameter progressively increased from 0 to 3. One readily notes that progressively increased stretching in one direction causes the emergence of a couple of well-distinguishable peaks together with some satellite peaks in accordance with the gradual structural change in a nanorice-like geometry. This result bears a remarkable resemblance to an experimental study exploring the multipolar plasmon resonance in silver nanorice,29 finding well-distinguishable longitudinal mode, transverse mode, and satellite peaks, although our structures are much smaller in size and different in nature. Before discussing the optical response of non-spherical nanoparticles, let us examine the optical response of a spherical nanoparticle (see Fig. 1). We observe that a spherical nanoparticle exhibits two peaks, one peak located between 3 and 3.5 eV and another located between 4 and 4.5 eV. By progressively increasing the stretching parameter from a small value of 0.5 to a larger value of 3, the optical response modifies drastically via the emergence of new additional peaks. This kind of spectral evolution is not unexpected since as the spherical nanoparticle gradually transforms into a nanorice-like geometry, one speculates the emergence of the longitudinal mode and the transverse mode together with some multi-polar satellite peaks. Briefly, for a small stretching parameter of 0.5, the longitudinal and transverse mode peaks appear centered around 3.2 and 4.1 eV, respectively, and on top of that satellite peaks also emerge centering around 2.5 eV. Upon further increasing the stretching parameter to 1, the longitudinal mode and transverse mode peaks slightly red-shift to 2.8 eV and 4.0 eV, respectively, together with a significant reduction in the spectral intensities. In addition, one sees that the satellite peaks are now located between 2 and 2.5 eV. By further increasing the stretching parameter to 1.5, significant spectral modifications come into play. For instance, the longitudinal peak blue-shifts by 0.2 eV having a slight enhancement in intensity while the spectral features of the transverse mode remain unchanged and the satellite peaks now appear around 2.4 eV. By further increasing the stretching parameter to 2, more dramatic differences appear, i.e., the longitudinal mode red-shifts by 0.2 eV with a significant reduction in the spectral intensity while the transverse peak gains an enhanced intensity while its energetic position remains unchanged and the satellite peaks appear around 2.25 eV. More dramatic spectral modifications emerge for a stretching parameter of 2.5, in which the longitudinal mode slightly blue-shifts together with a significant reduction in the spectral intensity, whereas a huge enhancement in the transverse peak emerges. Finally, for the largest stretching parameter of 3, we see well-distinguishable spectral features in which the longitudinal peak appears centered around 3.1 eV and the transverse peak appears centered around 4 eV. The above-mentioned findings are consistent with the nanorice spectral features reported previously.16 In brief, Fig. 1 reveals rich features in the evolution of the optical response. This is especially pronounced for the longitudinal peaks, which undergo considerable modifications in their features with respect to different amounts of stretching. This implies that the shape-anisotropy has a stronger influence on the optical response than just the shifting of the peak frequencies. Also we see that even small deviations from the spherical shape can cause huge effects on the optical response. We believe that the discontinuous shifts in the longitudinal peaks, transverse peaks and satellite peaks could be due to the coupling of unperturbed single particle–hole transitions with the collective electron oscillations.
Having explored the optical response evolution as a function of progressively increased stretching in one direction (see Fig. 1), we proceed to analyze the optical response evolution when the stretching process is applied in two directions. Toward this aim, we show in Fig. 2 the optical response as a function of the different stretching parameters from 0 to 3. Our preliminary analysis of Fig. 2 reveals that progressively increasing the stretching parameter causes multiple peaks to appear. This finding is not unexpected since the structural transformation from a highly symmetric to a less symmetric geometry causes different plasmon modes to interact with each other. This result is qualitatively in agreement with the shape-dependent plasmon response modifications studied by Prodan and coworkers using the plasmon hybridization theory.30 In brief, for a small stretching parameter of 0.5, the spectrum shows a couple of dominant peaks centered around 2.8 and 3.7 eV, respectively, and one low-intensity peak centered around 1.6 eV (see Fig. 2). A further increase in the stretching parameter to 1 causes dramatic changes in the spectrum, i.e. a strong peak appears centered around 3.7 eV with some satellite peaks located on both its shoulders. A further increase in the stretching parameter to 1.5 brings noteworthy changes in the spectral profile. One finds that the strong peak slightly red-shifts and splits into two close-lying peaks having almost similar intensities and also a low-intensity peak appears centered around 2.25 eV. Further tuning the stretching parameter to 2, one sees that the double-peak spectral profile slightly blue-shifts with a significant reduction in the intensity (see Fig. 2). A further increase in the stretching parameter to 2.5 causes a spectral blue-shift and a reduction in the intensity. Finally, for the highest stretching parameter of 3, we see remarkable spectral features, i.e., two strong and well-distinguishable peaks centered around 2.7 eV and 3.5 eV emerge. Overall, Fig. 2 shows the complex features in the optical response evolution. In order to check for size effects on the optical response evolution, we have performed the calculations for a 249 atom spherical nanoparticle (see Fig. 3) by stretching in one direction in which the stretching parameter progressively increased from 0 to 3. Fig. 3 confirms our previous conclusions on an 807 atom nanoparticle. Interestingly, cross-comparison of the 807 atom nanoparticle (see Fig. 1) and 249 atom nanoparticle (Fig. 3) optical responses shows one interesting effect. That is the highest peak absorption in both nanoparticles appears for a stretching parameter of 2.5. This simply means that 2.5 stretch induces more collective excitations compared to the rest of the stretching values. In addition, we have also calculated the effect of compression on the optical response finding that even a small compression results in a drastic reduction in the spectral intensity. Also note that the optical response modifications under compression are quite different from the stretching case since in the former (latter) a huge reduction (enhancement) in the spectral intensity can be observed.
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Fig. 3 TDDFT calculated optical spectra for stretching in one direction (249 atom nanoparticle) in which the stretching parameter progressively increased from 0 to 3. |
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